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The reduction of blowdown by dealkalization keeps the water treatment chemicals in the boiler longer, thus minimizing the amount of chemicals required for efficient, noncorrosive operation. [2] Carbonate and bicarbonate alkalinities are decomposed by heat in boiler water releasing carbon dioxide into the steam.
Where desired, free bromine may be obtained by thermal decomposition of ferrous bromide. [1] Before Dow entered the bromine business, brine was evaporated by heating with wood scraps and then crystallized sodium chloride was removed. An oxidizing agent was added, and bromine was formed in the solution. Then bromine was distilled.
Brine draw: Water is directed through a jet pump, which pulls salt water from the brine tank, before the water and brine pass through the resin bed in the normal direction, if co-current, or in the reverse direction, if counter-current. [12] The output of this typically thirty-minute process is discarded through the drain hose.
Water softeners are usually regenerated with brine containing 10% sodium chloride. [7] Aside from the soluble chloride salts of divalent cations removed from the softened water, softener regeneration wastewater contains the unused 50–70% of the sodium chloride regeneration flushing brine required to reverse ion-exchange resin equilibria.
In neutral solution, permanganate slowly reduces to manganese dioxide (MnO 2). This is the material that stains one's skin when handling KMnO 4. KMnO 4 reduces in alkaline solution to give green K 2 MnO 4: [75] 4 KMnO 4 + 4 KOH → 4 K 2 MnO 4 + O 2 + 2 H 2 O. This reaction illustrates the relatively rare role of hydroxide as a reducing agent.
The brine may be seawater, other surface water, groundwater, or hyper-saline solutions from several industries (e.g., textile industries). [1] It differs from solution mining or in-situ leaching in that those methods inject water or chemicals to dissolve materials which are in a solid state; in brine mining, the materials are already dissolved.
Dihydrate salt (NaBr·2H 2 O) crystallize out of water solution below 50.7 °C. [8] NaBr is produced by treating sodium hydroxide with hydrogen bromide. Sodium bromide can be used as a source of the chemical element bromine. This can be accomplished by treating an aqueous solution of NaBr with chlorine gas: 2 NaBr + Cl 2 → Br 2 + 2 NaCl
Potassium bromate is readily separated from the potassium bromide present in both methods owing to its much lower solubility; when a solution containing potassium bromate and bromide is cooled to 0°C, nearly all bromate will precipitate, while nearly all of the bromide will stay in solution. [2]
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