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  2. Determinant - Wikipedia

    en.wikipedia.org/wiki/Determinant

    These determinants are either 0 (by property 9) or else ±1 (by properties 1 and 12 below), so the linear combination gives the expression above in terms of the Levi-Civita symbol. While less technical in appearance, this characterization cannot entirely replace the Leibniz formula in defining the determinant, since without it the existence of ...

  3. Slater determinant - Wikipedia

    en.wikipedia.org/wiki/Slater_determinant

    The use of Slater determinants ensures an antisymmetrized function at the outset. In the same way, the use of Slater determinants ensures conformity to the Pauli principle. Indeed, the Slater determinant vanishes if the set {} is linearly dependent. In particular, this is the case when two (or more) spin orbitals are the same.

  4. Leibniz formula for determinants - Wikipedia

    en.wikipedia.org/wiki/Leibniz_formula_for...

    Instead, the determinant can be evaluated in () operations by forming the LU decomposition = (typically via Gaussian elimination or similar methods), in which case = and the determinants of the triangular matrices and are simply the products of their diagonal entries. (In practical applications of numerical linear algebra, however, explicit ...

  5. Cramer's rule - Wikipedia

    en.wikipedia.org/wiki/Cramer's_rule

    In the 2×2 case, if the coefficient determinant is zero, then the system is incompatible if the numerator determinants are nonzero, or indeterminate if the numerator determinants are zero. For 3×3 or higher systems, the only thing one can say when the coefficient determinant equals zero is that if any of the numerator determinants are nonzero ...

  6. Epitope - Wikipedia

    en.wikipedia.org/wiki/Epitope

    [12] [13] There are additional epitope types when the quaternary structure is considered. [13] Epitopes that are masked when protein subunits aggregate are called cryptotopes . [ 13 ] Neotopes are epitopes that are only recognized while in a specific quaternary structure and the residues of the epitope can span multiple protein subunits. [ 13 ]

  7. Hyperdeterminant - Wikipedia

    en.wikipedia.org/wiki/Hyperdeterminant

    In algebra, the hyperdeterminant is a generalization of the determinant.Whereas a determinant is a scalar valued function defined on an n × n square matrix, a hyperdeterminant is defined on a multidimensional array of numbers or tensor.

  8. Hessian matrix - Wikipedia

    en.wikipedia.org/wiki/Hessian_matrix

    Equivalently, the second-order conditions that are sufficient for a local minimum or maximum can be expressed in terms of the sequence of principal (upper-leftmost) minors (determinants of sub-matrices) of the Hessian; these conditions are a special case of those given in the next section for bordered Hessians for constrained optimization—the ...

  9. Quantities, Units and Symbols in Physical Chemistry

    en.wikipedia.org/wiki/Quantities,_Units_and...

    The Green Book is a direct successor of the Manual of Symbols and Terminology for Physicochemical Quantities and Units, originally prepared for publication on behalf of IUPAC's Physical Chemistry Division by M. L. McGlashen in 1969. A full history of the Green Book's various editions is provided in the historical introduction to the third edition.