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  2. Epoxidation of allylic alcohols - Wikipedia

    en.wikipedia.org/.../Epoxidation_of_allylic_alcohols

    The epoxidation of allylic alcohols is a class of epoxidation reactions in organic chemistry. One implementation of this reaction is the Sharpless epoxidation . Early work showed that allylic alcohols give facial selectivity when using meta-chloroperoxybenzoic acid (m-CPBA) as an oxidant.

  3. Base-promoted epoxide isomerization - Wikipedia

    en.wikipedia.org/wiki/Base-promoted_epoxide...

    Removal of a proton adjacent to the epoxide, elimination, and neutralization of the resulting alkoxide lead to synthetically useful allylic alcohol products. In reactions of chiral , non-racemic epoxides, the configuration of the allylic alcohol product matches that of the epoxide substrate at the carbon whose C–O bond does not break (the ...

  4. Sharpless epoxidation - Wikipedia

    en.wikipedia.org/wiki/Sharpless_epoxidation

    The Sharpless epoxidation is viable with a large range of primary and secondary alkenic alcohols. Furthermore, with the exception noted above, a given dialkyl tartrate will preferentially add to the same face independent of the substitution on the alkene.To demonstrate the synthetic utility of the Sharpless epoxidation, the Sharpless group created synthetic intermediates of various natural ...

  5. Tsuji–Trost reaction - Wikipedia

    en.wikipedia.org/wiki/Tsuji–Trost_reaction

    The Tsuji–Trost reaction (also called the Trost allylic alkylation or allylic alkylation) is a palladium-catalysed substitution reaction involving a substrate that contains a leaving group in an allylic position. The palladium catalyst first coordinates with the allyl group and then undergoes oxidative addition, forming the π-allyl

  6. Wharton reaction - Wikipedia

    en.wikipedia.org/wiki/Wharton_reaction

    The Wharton olefin synthesis allows the transformation of an α,β unsaturated ketone into an allylic alcohol. The epoxide starting material can be generated by a number of methods, with the most common being reaction of the corresponding alkene with hydrogen peroxide or m-chloroperoxybenzoic acid. The Wharton reaction also commonly suffers ...

  7. Allyl glycidyl ether - Wikipedia

    en.wikipedia.org/wiki/Allyl_glycidyl_ether

    The synthesis of allyl glycidyl ether by condensation of allyl alcohol and epichlorohydrin. AGE can also be synthesized by monoepoxidation of diallyl ether. [6] [7] The synthesis of allyl glycidyl ether by epoxidation of diallyl ether. Diepoxidation of the second alkene would produce diglycidyl ether. Allyl glycidyl ether is chiral.

  8. The 4 Worst Drinks If You’re Trying to Lose Visceral Fat ...

    www.aol.com/4-worst-drinks-youre-trying...

    A study examining different types of alcohol found that higher consumption of liquor and beer was associated with increased visceral fat in adults. This makes it even more important to moderate ...

  9. Kharasch–Sosnovsky reaction - Wikipedia

    en.wikipedia.org/wiki/Kharasch–Sosnovsky_reaction

    The Kharasch–Sosnovsky reaction is a method that involves using a copper or cobalt salt as a catalyst to oxidize olefins at the allylic position, subsequently condensing a peroxy ester (e.g. tert-Butyl peroxybenzoate) or a peroxide resulting in the formation of allylic benzoates or alcohols via radical oxidation. [1]