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The crystal structure of the skutterudite mineral was determined in 1928 by Oftedahl [7] [8] to be cubic, belonging to space group Im-3 (number 204). The unit cell can be considered to consist of eight smaller cubes made up of the Co atoms. Six of these cubes are filled with (almost) square planar rings of As, each of which is oriented parallel ...
Arsenic is also a common n-type dopant in semiconductor electronic devices, and a component of the III–V compound semiconductor gallium arsenide. Arsenic and its compounds, especially the trioxide, are used in the production of pesticides, treated wood products, herbicides, and insecticides. These applications are declining with the ...
The compound was characterized by computational and spectroscopic [2] [3] techniques and found to possess a cage-like structure similar to adamantane in which the four methanetriyl carbon bridgeheads are replaced by arsenic atoms and three of the six methylene bridges are replaced by oxygen atoms.
To give provisional names to his predicted elements, Dmitri Mendeleev used the prefixes eka- / ˈ iː k ə-/, [note 1] dvi- or dwi-, and tri-, from the Sanskrit names of digits 1, 2, and 3, [3] depending upon whether the predicted element was one, two, or three places down from the known element of the same group in his table.
In its standard state arsine is a colorless, denser-than-air gas that is slightly soluble in water (2% at 20 °C) [1] and in many organic solvents as well. [citation needed] Arsine itself is odorless, [5] but it oxidizes in air and this creates a slight garlic or fish-like scent when the compound is present above 0.5 ppm. [6]
Gray, or metallic arsenic, pictured under an argon atmosphere. Gray arsenic, also called grey arsenic or metallic arsenic, is the most stable allotrope of the element at room temperature, and as such is its most common form. [1] This soft, brittle allotrope of arsenic has a steel gray, metallic color, and is a good conductor. [2]
Realgar (/ r i ˈ æ l ɡ ɑːr,-ɡ ər / ree-AL-gar, -gər), also known as arsenic blende, ruby sulphur or ruby of arsenic, is an arsenic sulfide mineral with the chemical formula α-As 4 S 4. It is a soft, sectile mineral occurring in monoclinic crystals, or in granular, compact, or powdery form, often in association with the related ...
Anthropogenic (man-made) sources of arsenic, like the natural sources, are mainly arsenic oxides and the associated anions. Man-made sources of arsenic, include wastes from mineral processing, swine and poultry farms. [16] For example, many ores, especially sulfide minerals, are contaminated with arsenic, which is released in roasting (burning ...