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Black phosphorus is the thermodynamically stable form of phosphorus at room temperature and pressure, with a heat of formation of −39.3 kJ/mol (relative to white phosphorus which is defined as the standard state). [1]
Black phosphorus is likely to be the layered semiconductor material with the highest carrier mobility at room temperature, making it promising for high-performance electronic applications.
This review provides a comprehensive exploration of black phosphorus, covering its crystal structure, phase transition process, unique physical properties, and diverse synthesis methods (both bottom-up and top-down approaches, especially the methods of growing large-scale and high-crystalline products).
Black phosphorus (BP), a fascinating semiconductor with high mobility and a tunable direct bandgap, has emerged as a candidate beyond traditional silicon-based devices for next-generation...
Black phosphorus (BP), as a layered semiconductor with controllable bandgap and high carrier mobility, is one of the most promising candidates for transistor devices at atomistic thickness1–4.
The main characteristics of black phosphorus such as a strong thickness-dependent band structure or marked in-plane anisotropy are discussed, and the recent works applying black phosphorus for electronic, optics, and mechanical nanodevices are summarized.
One hundred years after its first successful synthesis in the bulk form in 1914, black phosphorus (black P) was recently rediscovered from the perspective of a 2D layered material, attracting tremendous interest from condensed matter physicists, chemists, semiconductor device engineers, and material scientists.
Black phosphorus (BP), a rediscovered two-dimensional (2D) material, has garnered significant interest due to its unique structure and physicochemical characteristics, including adjustable direct bandgaps, high carrier mobility, large specific surface area, and pronounced chemical reactivity.
Black phosphorus (BP) is one of the most stable allotropes among the three allotropes of phosphorus at a high temperature under a high pressure possessing new two-dimensional layered structure, which was first prepared by Bridgman in 1914.
The recent isolation of atomically thin black phosphorus by mechanical exfoliation of bulk layered crystals has triggered an unprecedented interest, even higher than that raised by the first works on graphene and other two-dimensionals, in the nanoscience and nanotechnology community.