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Simplified diagram of the Copper–Chlorine cycle. The copper–chlorine cycle (Cu–Cl cycle) is a four-step thermochemical cycle for the production of hydrogen. The Cu–Cl cycle is a hybrid process that employs both thermochemical and electrolysis steps. It has a maximum temperature requirement of about 530 degrees Celsius. [1]
Copper(II) chloride catalyzes the chlorination in the production of vinyl chloride and dichloromethane. [8] Copper(II) chloride is used in the copper–chlorine cycle where it reacts with steam into copper(II) oxide dichloride and hydrogen chloride and is later recovered in the cycle from the electrolysis of copper(I) chloride. [11]
Electrolysis of iron can eliminate direct emissions and further reduce emissions if the electricity is created from green energy. The small-scale electrolysis of iron has been successfully reported by dissolving it in molten oxide salts and using a platinum anode. [52] Oxygen anions form oxygen gas and electrons at the anode.
Electrolysis is usually done in bulk using hundreds of sheets of metal connected to an electric power source. In the production of copper, these pure sheets of copper are used as starter material for the cathodes, and are then lowered into a solution such as copper sulfate with the large anodes that are cast from impure (97% pure) copper.
The process was based on the oxidation of hydrogen chloride: 4 HCl + O 2 → 2 Cl 2 + 2H 2 O. The reaction takes place at about 400 to 450 °C in the presence of a variety of catalysts, including copper chloride (CuCl 2). Three companies developed commercial processes for producing chlorine based on the Deacon reaction: [1]
Electrolysis (a.k.a. electrolytic refining) Rubidium Rb Rb + Potassium K K + Sodium Na Na + Lithium Li Li + Barium Ba Ba 2+ Strontium Sr Sr 2+ Calcium Ca Ca 2+ Magnesium Mg Mg 2+ reacts very slowly with cold water, but rapidly in boiling water, and very vigorously with acids: Beryllium Be Be 2+ reacts with acids and steam Aluminium Al Al 3 ...
Copper fluoroborate baths are similar to acid sulfate baths, but they use fluoroborate as the anion rather than sulfate. [6] Copper fluoroborate is much more soluble than copper sulfate, which allows one to dissolve larger quantities of copper salt into the bath, enabling much higher current densities than what is possible in copper sulfate baths.
Pourbaix diagram of iron. [1] The Y axis corresponds to voltage potential. In electrochemistry, and more generally in solution chemistry, a Pourbaix diagram, also known as a potential/pH diagram, E H –pH diagram or a pE/pH diagram, is a plot of possible thermodynamically stable phases (i.e., at chemical equilibrium) of an aqueous electrochemical system.