Search results
Results from the WOW.Com Content Network
In IUPAC nomenclature, an acetyl group is called an ethanoyl group. An acetyl group contains a methyl group (−CH 3) that is single-bonded to a carbonyl (C=O), making it an acyl group. The carbonyl center of an acyl radical has one non-bonded electron with which it forms a chemical bond to the remainder (denoted with the letter R) of the molecule.
Used in a more general sense, the term X,Y-acetal also refers to any functional group that consists of a carbon bearing two heteroatoms X and Y. For example, N,O-acetal refers to compounds of type R 1 R 2 C(OR)(NR' 2) (R,R' ≠ H) also known as a hemiaminal ether or Aminal, a.k.a. aminoacetal.
Acid catalyzed acetal formation from the corresponding hemiacetal. Acetals, as already pointed out, are stable tetrahedral intermediates so they can be used as protective groups in organic synthesis. Acetals are stable under basic conditions, so they can be used to protect ketones from a base. The acetal group is hydrolyzed under acidic conditions.
The reactivity of a functional group can be modified by other functional groups nearby. Functional group interconversion can be used in retrosynthetic analysis to plan organic synthesis. A functional group is a group of atoms in a molecule with distinctive chemical properties, regardless of the other atoms in the molecule.
It introduces an acetyl group into a chemical compound. Such compounds are termed acetate esters or simply acetates. Deacetylation is the opposite reaction, the removal of an acetyl group from a chemical compound.
Get AOL Mail for FREE! Manage your email like never before with travel, photo & document views. Personalize your inbox with themes & tabs. You've Got Mail!
The latter reagent in itself is an acetal and therefore the reaction is actually a cross-acetalisation. Kinetic reaction control results from 2-methoxypropene as the reagent. D-ribose in itself is a hemiacetal and in equilibrium with the pyranose 3. In aqueous solution ribose is 75% pyranose and 25% furanose and a different acetal 4 is formed.
x. AOL funktioniert am besten mit den neuesten Versionen der Browser. Sie verwenden einen veralteten oder nicht unterstützten Browser; möglicherweise funktionieren einige Funktionen von AOL nicht richtig.