Search results
Results from the WOW.Com Content Network
This kind of chromic acid may be used as a cleaning mixture for glass. Chromic acid may also refer to the molecular species, H 2 CrO 4 of which the trioxide is the anhydride. Chromic acid features chromium in an oxidation state of +6 (and a valence of VI or 6). It is a strong and corrosive oxidizing agent and a moderate carcinogen.
For oxidations to the aldehydes and ketones, two equivalents of chromic acid oxidize three equivalents of the alcohol: 2 HCrO 4 − + 3 RR'C(OH)H + 8 H + + 4 H 2 O → 2 [Cr(H 2 O) 6] 3+ + 3 RR'CO. For oxidation of primary alcohols to carboxylic acids, 4 equivalents of chromic acid oxidize 3 equivalents of the alcohol. The aldehyde is an ...
Chromium trioxide (also known as chromium(VI) oxide or chromic anhydride) is an inorganic compound with the formula CrO 3. It is the acidic anhydride of chromic acid, and is sometimes marketed under the same name. [6] This compound is a dark-purple solid under anhydrous conditions and bright orange when wet. The substance dissolves in water ...
The red line on the predominance diagram is not quite horizontal due to the simultaneous equilibrium with the chromate ion. The hydrogen chromate ion may be protonated, with the formation of molecular chromic acid, H 2 CrO 4, but the pK a for the equilibrium H 2 CrO 4 ⇌ HCrO − 4 + H + is not well characterized.
It is a vaguely described chemical, despite many well-defined chromates and dichromates being known. The dark red chromium(VI) oxide CrO 3, the acid anhydride of chromic acid, is sold industrially as "chromic acid". [6] It can be produced by mixing sulfuric acid with dichromate and is a strong oxidizing agent.
Potassium dichromate, Chromic acid, (K2CrO4), dipotassium salt. ... It is a common laboratory chemical, whereas sodium chromate is important industrially.
Chromium(III) sulfate are commonly obtained from the wastes of chromate oxidations of various organic compounds. Anthraquinone and quinone are produced on large scale by the x treatment of respectively anthracene and phenol with chromic acid. A chromium(III) oxide byproduct is generated, which is readily extracted into sulfuric acid.
Chromium(III) oxide is amphoteric. Although insoluble in water, it reacts with acid to produce salts of hydrated chromium ions such as [Cr(H 2 O) 6] 3+. [10] It is also attacked by concentrated alkali to yield salts of [Cr(OH) 6] 3−. When heated with finely divided carbon or aluminium, it is reduced to chromium metal: Cr 2 O 3 + 2 Al → 2 Cr ...