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Polyhedral representation of spinel MgAl 2 O 4. Spinel (/ s p ɪ ˈ n ɛ l, ˈ s p ɪ n əl / [7]) is the magnesium/aluminium member of the larger spinel group of minerals. It has the formula MgAl 2 O 4 in the cubic crystal system. Its name comes from the Latin word spinella, a diminutive form of spine, in reference to its pointed crystals. [5]
It is primarily used to produce the ruby, sapphire and padparadscha varieties of corundum, as well as the diamond simulants rutile, strontium titanate and spinel. The principle of the process involves melting a finely powdered substance using an oxyhydrogen flame, and crystallising the melted droplets into a boule.
Following the successful synthesis of ruby, Verneuil focused his efforts on sapphire. Synthesis of blue sapphire came in 1909, after chemical analyses of sapphire suggested to Verneuil that iron and titanium were the cause of the blue color. Verneuil patented the process of producing synthetic blue sapphire in 1911. [49] [5]: 254–255
Blue-violet National Museum of Natural History, Washington [9] Star of Bombay: Sri Lanka 182 carats (36.4 g) Star Blue-violet National Museum of Natural History, Washington [10] Ruspoli Sapphire: 136.9 carats (27.38 g) [11] Stuart Sapphire: Sri Lanka 104 carats (20.8 g) Blue Tower of London [12] Bismarck Sapphire: Myanmar: 98.56 carats (19.712 ...
Inverse spinel structures have a different cation distribution in that all of the A cations and half of the B cations occupy octahedral sites, while the other half of the B cations occupy tetrahedral sites. An example of an inverse spinel is Fe 3 O 4, if the Fe 2+ (A 2+) ions are d 6 high-spin and the Fe 3+ (B 3+) ions are d 5 high-spin.
Corundum is a crystalline form of aluminium oxide (Al 2 O 3) typically containing traces of iron, titanium, vanadium, and chromium. [3] [4] It is a rock-forming mineral.It is a naturally transparent material, but can have different colors depending on the presence of transition metal impurities in its crystalline structure. [7]
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