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[12] [13] Copper(II) chloride reacts with several metals to produce copper metal or copper(I) chloride (CuCl) with oxidation of the other metal. To convert copper(II) chloride to copper(I) chloride, it can be convenient to reduce an aqueous solution with sulfur dioxide as the reductant: [8] 2 CuCl 2 + SO 2 + 2 H 2 O → 2 CuCl + 2 HCl + H 2 SO 4
The main use of copper(I) chloride is as a precursor to the fungicide copper oxychloride. For this purpose aqueous copper(I) chloride is generated by comproportionation and then air-oxidized: [12] Cu + CuCl 2 → 2 CuCl 4 CuCl + O 2 + 2 H 2 O → Cu 3 Cl 2 (OH) 4 + CuCl 2. Copper(I) chloride catalyzes a variety of organic reactions, as
A solution of zinc chloride in hydrochloric acid is a common flux for stainless steels; it has however to be thoroughly removed afterwards as it would cause pitting corrosion. Another highly effective flux is phosphoric acid; its tendency to polymerize at higher temperatures however limits its applications.
For these and similar reasons, the use of aluminium chloride has often been displaced by zeolites. [7] Aluminium chloride can also be used to introduce aldehyde groups onto aromatic rings, for example via the Gattermann-Koch reaction which uses carbon monoxide, hydrogen chloride and a copper(I) chloride co-catalyst. [19]
The flame test carried out on a copper halide. The characteristic bluish-green color of the flame is due to the copper. A flame test is relatively quick test for the presence of some elements in a sample. The technique is archaic and of questionable reliability, but once was a component of qualitative inorganic analysis.
This experiment in chemistry is usually performed by adding metal salts, such as copper sulfate or cobalt(II) chloride, to an aqueous solution of sodium silicate (otherwise known as waterglass). This results in the growth of plant-like forms in minutes to hours. [1] [2] [3] [4]
A metal ion in aqueous solution or aqua ion is a cation, dissolved in water, of chemical formula [M(H 2 O) n] z+.The solvation number, n, determined by a variety of experimental methods is 4 for Li + and Be 2+ and 6 for most elements in periods 3 and 4 of the periodic table.
Black for aluminum. Boil a solution of 20 g ammonium molybdate and 5 g of sodium thiosulfate in a liter of water, immerse the objects, rinse, dry, wax or lacquer after the development of color. [31] Lustre colours. Use a solution of 280 g of sodium thiosulphate, 25 g of cupric acetate and 30 g of citric acid. It can be used on copper and its ...