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Notable examples include sublimation of dry ice at room temperature and atmospheric pressure, and that of solid iodine with heating. The reverse process of sublimation is deposition (also called desublimation), in which a substance passes directly from a gas to a solid phase, without passing through the liquid state. [4]
The sublimation sandwich method (also called the sublimation sandwich process and the sublimation sandwich technique) is a kind of physical vapor deposition used for creating man-made crystals. Silicon carbide is the most common crystal grown this way, though other crystals may also be created with it (notably gallium nitride ).
A sublimatory [1] [2] or sublimation apparatus is equipment, commonly laboratory glassware, for purification of compounds by selective sublimation. In principle, the operation resembles purification by distillation , except that the products do not pass through a liquid phase .
This list is sorted by boiling point of gases in ascending order, but can be sorted on different values. "sub" and "triple" refer to the sublimation point and the triple point, which are given in the case of a substance that sublimes at 1 atm; "dec" refers to decomposition. "~" means approximately.
The low temperature and direct sublimation to a gas makes dry ice an effective coolant, since it is colder than water ice and leaves no residue as it changes state. [4] Its enthalpy of sublimation is 571 kJ/kg (25.2 kJ/mol, 136.5 calorie/g). Dry ice is non-polar, with a dipole moment of zero, so attractive intermolecular van der Waals forces ...
Microwave-assisted freeze dryers utilize microwaves to allow for deeper penetration into the sample to expedite the sublimation and heating processes in freeze-drying. This method can be complicated to set up and run as the microwaves can create an electrical field capable of causing gases in the sample chamber to become plasma.
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Outgassing can be significant if it collects in a closed environment where air is stagnant or recirculated. For example, new car smell consists of outgassed chemicals released by heat in a closed automobile. Even a nearly odorless material such as wood may build up a strong smell if kept in a closed box for months.