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  2. Non-linear effects - Wikipedia

    en.wikipedia.org/wiki/Non-linear_effects

    If the correction factor is greater than one, the reaction displays an asymmetric amplification, also known as a positive non-linear effect. Under the ML 2 model, a (+)-NLE infers a less reactive heterochiral catalyst. In this case, the equilibrium constant K also increases as the correction factor increases.

  3. Amott test - Wikipedia

    en.wikipedia.org/wiki/Amott_test

    The Amott test is one of the most widely used empirical wettability measurements for reservoir cores in petroleum engineering.The method combines two spontaneous imbibition measurements and two forced displacement measurements.

  4. Reference electrode - Wikipedia

    en.wikipedia.org/wiki/Reference_electrode

    5) Reservoir via which the second half-element of the galvanic cell should be attached. The connection can be direct, through a narrow tube to reduce mixing, or through a salt bridge, depending on the other electrode and solution. This creates an ionically conductive path to the working electrode of interest.

  5. Host–guest chemistry - Wikipedia

    en.wikipedia.org/wiki/Host–guest_chemistry

    In supramolecular chemistry, [1] host–guest chemistry describes complexes that are composed of two or more molecules or ions that are held together in unique structural relationships by forces other than those of full covalent bonds. Host–guest chemistry encompasses the idea of molecular recognition and interactions through non-covalent ...

  6. Fundamental resolution equation - Wikipedia

    en.wikipedia.org/wiki/Fundamental_Resolution...

    The [N 1/2 /4] term is the column factor, the [(α-1)/α] term is the thermodynamic factor, and the [k 2 '/(1+k 2 ')] term is the retention factor. The 3 factors are not completely independent, but they are very close, and can be treated as such.

  7. Taft equation - Wikipedia

    en.wikipedia.org/wiki/Taft_equation

    The polar sensitivity factor ρ* can be obtained by plotting the ratio of the measured reaction rates (k s) compared to the reference reaction versus the σ* values for the substituents. This plot will give a straight line with a slope equal to ρ*. Similar to the Hammett ρ value:

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  9. Response factor - Wikipedia

    en.wikipedia.org/wiki/Response_factor

    The response factor can be expressed on a molar, volume or mass [1] basis. Where the true amount of sample and standard are equal: = where A is the signal (e.g. peak area) and the subscript i indicates the sample and the subscript st indicates the standard. [2]