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Penning ionization is a form of chemi-ionization, an ionization process involving reactions between neutral atoms or molecules. [1] [2] The Penning effect is put to practical use in applications such as gas-discharge neon lamps and fluorescent lamps, where the lamp is filled with a Penning mixture to improve the electrical characteristics of the lamps.
Gas phase ion chemistry is a field of science encompassed within both chemistry and physics. It is the science that studies ions and molecules in the gas phase, most often enabled by some form of mass spectrometry. By far the most important applications for this science is in studying the thermodynamics and kinetics of reactions.
A Penning mixture is a mixture of gases that is used in electric gas-discharge lamps. It is defined as a mixture of one inert gas with a minute amount of another gas, one that has lower ionization voltage than the main constituent. It is named after Frans Michel Penning. [1] [2]
Chemi-ionization is the formation of an ion through the reaction of a gas phase atom or molecule with another atom or molecule when the collision energy is below the energy required to ionize the reagents. [1] [2] The reaction may involve a reagent in an excited state [3] or may result in the formation of a new chemical bond.
The basic element of the common ion pump is a Penning trap. [6] A swirling cloud of electrons produced by an electric discharge is temporarily stored in the anode region of a Penning trap. These electrons ionize incoming gas atoms and molecules. The resultant swirling ions are accelerated to strike a chemically active cathode (usually titanium ...
Electron capture ionization (ECI) is the ionization of a gas phase atom or molecule by attachment of an electron to create an ion of the form A −•.The reaction is + where the M over the arrow denotes that to conserve energy and momentum a third body is required (the molecularity of the reaction is three).
The DART ion source is a kind of gas-phase ionization, and it requires some sort of volatility of the analyte to support thermally assisted desorption of analyte ions. [14] This limits the size range of the molecules that can be analyzed by DART i.e. m/z 50 to 1200. [1] [15] DART-MS is capable of semi-quantitative and quantitative analysis. To ...
The ability to couple gas chromatography with a low-fragmentation ionization technique on an LC-MS, for example, can be utilized in the analysis of saturated hydrocarbons. Electron impact ionization commonly used in GC-MS leads to difficult-to-interpret fragmentation spectra, while plasma ionization provides fragmentation-free spectra. [7]
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