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Sodium bicarbonate can sometimes be used as a mild neutralization agent and a safer alternative to strong bases like sodium hydroxide. [79] Reaction of sodium bicarbonate and an acid produces a salt and carbonic acid, which readily decomposes to carbon dioxide and water: [79] NaHCO 3 + HCl → NaCl + H 2 O+CO 2 H 2 CO 3 → H 2 O + CO 2 (g)
The Solvay process or ammonia–soda process is the major industrial process for the production of sodium carbonate (soda ash, Na 2 CO 3).The ammonia–soda process was developed into its modern form by the Belgian chemist Ernest Solvay during the 1860s. [1]
Sodium carbonate is soluble in water, and can occur naturally in arid regions, especially in mineral deposits (evaporites) formed when seasonal lakes evaporate. Deposits of the mineral natron have been mined from dry lake bottoms in Egypt since ancient times, when natron was used in the preparation of mummies and in the early manufacture of glass.
When combined with water, the sodium bicarbonate and acid salts react to produce gaseous carbon dioxide. Whether commercially or domestically prepared, the principles behind baking powder formulations remain the same. The acid-base reaction can be generically represented as shown: [7] NaHCO 3 + H + → Na + + CO 2 + H 2 O
Catalyzed by carbonic anhydrase, carbon dioxide (CO 2) reacts with water (H 2 O) to form carbonic acid (H 2 CO 3), which in turn rapidly dissociates to form a bicarbonate ion (HCO − 3 ) and a hydrogen ion (H + ) as shown in the following reaction: [ 2 ] [ 3 ] [ 4 ]
Examples of important inorganic sodium salts are sodium fluoride, sodium chloride, sodium bromide, sodium iodide, sodium sulfate, sodium bicarbonate and sodium carbonate. Sodium amide (NaNH 2) is the sodium salt of ammonia (NH 3).
Bicarbonate is the dominant form of dissolved inorganic carbon in sea water, [9] and in most fresh waters. As such it is an important sink in the carbon cycle . Some plants like Chara utilize carbonate and produce calcium carbonate (CaCO 3 ) as result of biological metabolism.
Saponification is a process of cleaving esters into carboxylate salts and alcohols by the action of aqueous alkali.Typically aqueous sodium hydroxide solutions are used. [1] [2] It is an important type of alkaline hydrolysis.