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Polarizability increases down on columns of the periodic table. [9] Likewise, larger molecules are generally more polarizable than smaller ones. Water is a very polar molecule, but alkanes and other hydrophobic molecules are more polarizable. Water with its permanent dipole is less likely to change shape due to an external electric field.
This is known as the constitutive equation for electric fields. Here ε 0 is the electric permittivity of empty space. In this equation, P is the (negative of the) field induced in the material when the "fixed" charges, the dipoles, shift in response to the total underlying field E , whereas D is the field due to the remaining charges, known as ...
In electromagnetism, the absolute permittivity, often simply called permittivity and denoted by the Greek letter ε , is a measure of the electric polarizability of a dielectric material. A material with high permittivity polarizes more in response to an applied electric field than a material with low permittivity, thereby storing more energy ...
where μ is the electric dipole moment of the effectively polarized water molecule (2.35 D for the SPC/E model), μ 0 is the dipole moment of an isolated water molecule (1.85 D from experiment), and α i is an isotropic polarizability constant, with a value of 1.608 × 10 −40 F·m 2. Since the charges in the model are constant, this ...
The correlation should, however, be treated with caution. For instance, dichloromethane has a value of ε r of 9.08 (20 °C) and is rather poorly soluble in water (13 g/L or 9.8 mL/L at 20 °C); at the same time, tetrahydrofuran has its ε r = 7.52 at 22 °C, but it is completely miscible with water
In many materials the polarizability starts to saturate at high values of electric field. This saturation can be modelled by a nonlinear susceptibility . These susceptibilities are important in nonlinear optics and lead to effects such as second-harmonic generation (such as used to convert infrared light into visible light, in green laser ...
An object with an electric dipole moment p is subject to a torque τ when placed in an external electric field E. The torque tends to align the dipole with the field. A dipole aligned parallel to an electric field has lower potential energy than a dipole making some non-zero angle with it.
Surface tension is the tendency of liquid surfaces at rest to shrink into the minimum surface area possible. Surface tension is what allows objects with a higher density than water such as razor blades and insects (e.g. water striders) to float on a water surface without becoming even partly submerged.