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  2. List of unsolved problems in chemistry - Wikipedia

    en.wikipedia.org/wiki/List_of_unsolved_problems...

    This is a list of unsolved problems in chemistry. Problems in chemistry are considered unsolved when an expert in the field considers it unsolved or when several experts in the field disagree about a solution to a problem.

  3. Bromine test - Wikipedia

    en.wikipedia.org/wiki/Bromine_test

    In organic chemistry, the bromine test is a qualitative test for the presence of unsaturation (carbon-to-carbon double or triple bonds), phenols and anilines. An unknown sample is treated with a small amount of elemental bromine in an organic solvent, being as dichloromethane or carbon tetrachloride. Presence of unsaturation and/or phenol or ...

  4. Mass spectral interpretation - Wikipedia

    en.wikipedia.org/wiki/Mass_spectral_interpretation

    It is commonly used for the identification of organic compounds from electron ionization mass spectrometry. [ 3 ] [ 4 ] Organic chemists obtain mass spectra of chemical compounds as part of structure elucidation and the analysis is part of many organic chemistry curricula.

  5. List of chemical databases - Wikipedia

    en.wikipedia.org/wiki/List_of_chemical_databases

    organic, inorganic chemicals, proteins CASNo paid access only 130,000,000 ScrubChem scraped from PubChem "ScrubChem". 2,282,992 SDBS: Spectral Database for Organic Compounds National Institute of Advanced Industrial Science and Technology (AIST), Japan Organic compounds Spectra:IR Raman MASS ESR 1 H NMR 13 C NMR SDBS No curated "SDBS". 34,000

  6. Rate-determining step - Wikipedia

    en.wikipedia.org/wiki/Rate-determining_step

    Another example is the unimolecular nucleophilic substitution (S N 1) reaction in organic chemistry, where it is the first, rate-determining step that is unimolecular. A specific case is the basic hydrolysis of tert-butyl bromide (t-C 4 H 9 Br) by aqueous sodium hydroxide. The mechanism has two steps (where R denotes the tert-butyl radical t-C ...

  7. Le Bel–Van 't Hoff rule - Wikipedia

    en.wikipedia.org/wiki/Le_Bel–Van_'t_Hoff_rule

    In organic chemistry, the Le Bel–Van 't Hoff rule states that the number of stereoisomers of an organic compound containing no internal planes of symmetry is 2 n, where n represents the number of asymmetric carbon atoms.

  8. Reaction mechanism - Wikipedia

    en.wikipedia.org/wiki/Reaction_mechanism

    In chemistry, a reaction mechanism is the step by step sequence of elementary reactions by which overall chemical reaction occurs. [1] A chemical mechanism is a theoretical conjecture that tries to describe in detail what takes place at each stage of an overall chemical reaction. The detailed steps of a reaction are not observable in most cases.

  9. Hammett equation - Wikipedia

    en.wikipedia.org/wiki/Hammett_equation

    In organic chemistry, the Hammett equation describes a linear free-energy relationship relating reaction rates and equilibrium constants for many reactions involving benzoic acid derivatives with meta- and para-substituents to each other with just two parameters: a substituent constant and a reaction constant.