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The standard atmosphere was originally defined as the pressure exerted by a 760 mm column of mercury at 0 °C (32 °F) and standard gravity (g n = 9.806 65 m/s 2). [2] It was used as a reference condition for physical and chemical properties, and the definition of the centigrade temperature scale set 100 °C as the boiling point of water at this pressure.
Atmospheric pressure, also known as air pressure or barometric pressure (after the barometer), is the pressure within the atmosphere of Earth.The standard atmosphere (symbol: atm) is a unit of pressure defined as 101,325 Pa (1,013.25 hPa), which is equivalent to 1,013.25 millibars, [1] 760 mm Hg, 29.9212 inches Hg, or 14.696 psi. [2]
At 101.325 kPa (abs) and 15 °C (59 °F), air has a density of approximately 1.225 kg/m 3 (0.0765 lb/cu ft), which is about 1 ⁄ 800 that of water, according to the International Standard Atmosphere (ISA). [citation needed] Pure liquid water is 1,000 kg/m 3 (62 lb/cu ft).
The International Civil Aviation Organization (ICAO) published their "ICAO Standard Atmosphere" as Doc 7488-CD in 1993. It has the same model as the ISA, but extends the altitude coverage to 80 kilometers (262,500 feet). [7] The ICAO Standard Atmosphere, like the ISA, does not contain water vapor. Some of the values defined by ICAO are:
1 Nm 3 of any gas (measured at 0 °C and 1 atmosphere of absolute pressure) equals 37.326 scf of that gas (measured at 60 °F and 1 atmosphere of absolute pressure). 1 kmol of any ideal gas equals 22.414 Nm 3 of that gas at 0 °C and 1 atmosphere of absolute pressure ... and 1 lbmol of any ideal gas equals 379.482 scf of that gas at 60 °F and ...
The reference value for ρ b for b = 0 is the defined sea level value, ρ 0 = 1.2250 kg/m 3 or 0.0023768908 slug/ft 3. Values of ρ b of b = 1 through b = 6 are obtained from the application of the appropriate member of the pair equations 1 and 2 for the case when h = h b+1. [2]
The ideal gas equation can be rearranged to give an expression for the molar volume of an ideal gas: = = Hence, for a given temperature and pressure, the molar volume is the same for all ideal gases and is based on the gas constant: R = 8.314 462 618 153 24 m 3 ⋅Pa⋅K −1 ⋅mol −1, or about 8.205 736 608 095 96 × 10 −5 m 3 ⋅atm⋅K ...
The ambient pressure at sea level is approximately one atmosphere, which is equal to 1.01325 bars (14.6959 psi), which is close enough for bar and atm to be used interchangeably in many applications. In underwater diving the industry convention is to measure ambient pressure in terms of water column.