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Lewis dot structure of a Hydroxide ion compared to a hydroxyl radical. In chemistry, a radical, also known as a free radical, is an atom, molecule, or ion that has at least one unpaired valence electron. [1] [2] With some exceptions, these unpaired electrons make radicals highly chemically reactive. Many radicals spontaneously dimerize. Most ...
Most notably hydroxyl radicals are produced from the decomposition of hydroperoxides (ROOH) or, in atmospheric chemistry, by the reaction of excited atomic oxygen with water. It is also an important radical formed in radiation chemistry, since it leads to the formation of hydrogen peroxide and oxygen , which can enhance corrosion and stress ...
Chlorine, for example, gives two chlorine radicals (Cl•) by irradiation with ultraviolet light. This process is used for chlorination of alkanes . Azo compounds (R- N =N-R') can be the precursor of two carbon -centered radicals (R• and R'•) and nitrogen gas upon heating and/or by irradiation.
For instance, the t-butyl radical has a bond angle of 118° with a 0.7 kcal/mol (2.9 kJ/mol) barrier to pyramidal inversion. On the other hand, substitution of hydrogen atoms by more electronegative substituents leads to radicals with a strongly pyramidal geometry (112°), such as the trifluoromethyl radical, CF •
In organic chemistry, a radical anion is a free radical species [1] that carries a negative charge. Radical anions are encountered in organic chemistry as reduced derivatives of polycyclic aromatic compounds, e.g. sodium naphthenide. An example of a non-carbon radical anion is the superoxide anion, formed by transfer of one electron to an ...
Radicals can undergo a disproportionation reaction through a radical elimination mechanism (See Fig. 1). Here a radical abstracts a hydrogen atom from another same radical to form two non-radical species: an alkane and an alkene. Radicals can also undergo an elimination reaction to generate a new radical as the leaving group.
The sodium ion is an example of a cationic species and its formula is Na +. Species with an overall negative charge will be an anionic species. Chloride is an anionic species, and its formula is Cl −. [7] Radical species: Molecules or atoms with unpaired electrons. Triarlborane anion is a radical species and its formula is Ar3B − [8] [9]
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