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Following is a table of the change in the boiling point of water with elevation, at intervals of 500 meters over the range of human habitation [the Dead Sea at −430.5 metres (−1,412 ft) to La Rinconada, Peru at 5,100 m (16,700 ft)], then of 1,000 meters over the additional range of uninhabited surface elevation [up to Mount Everest at 8,849 ...
For pressures above 1 bar, that means, above the normal boiling point, the typical errors are below 2%. [2] Example calculation ... Goff–Gratch equation; References
The entropy of vaporization of XeF 6 at its boiling point has the extraordinarily high value of 136.9 J/(K·mol). [4] The characteristic of those liquids to which Trouton’s rule cannot be applied is their special interaction between molecules, such as hydrogen bonding. The entropy of vaporization of water and ethanol shows positive deviance ...
A variant of this single set approach is using a special parameter set fitted for the examined temperature range. The second solution is switching to another vapor pressure equation with more than three parameters. Commonly used are simple extensions of the Antoine equation (see below) and the equations of DIPPR or Wagner. [2] [3]
The boiling point of water is the temperature at which the saturated vapor pressure equals the ambient pressure. Water supercooled below its normal freezing point has a higher vapor pressure than that of ice at the same temperature and is, thus, unstable. Calculations of the (saturation) vapor pressure of water are commonly used in meteorology.
The boiling point elevation happens both when the solute is an electrolyte, such as various salts, and a nonelectrolyte. In thermodynamic terms, the origin of the boiling point elevation is entropic and can be explained in terms of the vapor pressure or chemical potential of the solvent. In both cases, the explanation depends on the fact that ...
A pressure hypsometer as shown in the drawing (right) employs the principle that the boiling point of a liquid is lowered by diminishing the barometric pressure, and that the barometric pressure varies with the height of the point of observation.
The Siwoloboff method is used to determine the boiling point of small samples of liquid chemicals. A sample in an ignition tube (also called a fusion tube) is attached to a thermometer with a rubber band, and immersed in a Thiele tube , water bath, or other suitable medium for heating.