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The excited, triplet state photosensitizer then reacts with a substrate molecule which is not molecular oxygen to both form a product and reform the photosensitizer. Type I photosensitized reactions result in the photosensitizer being quenched by a different chemical substrate than molecular oxygen.
Triplet chlorophyll is a potent photosensitiser of molecular oxygen forming singlet oxygen which can cause oxidative damage to the pigments, lipids and proteins of the photosynthetic thylakoid membrane. To counter this problem, one photoprotective mechanism is so-called non-photochemical quenching (NPQ), which relies upon the conversion and ...
This small difference makes chlorophyll b absorb light with wavelengths between 400 and 500 nm more efficiently. Carotenoids are long linear organic molecules that have alternating single and double bonds along their length. Such molecules are called polyenes. Two examples of carotenoids are lycopene and β-carotene. These molecules also absorb ...
The light-harvesting complex (or antenna complex; LH or LHC) is an array of protein and chlorophyll molecules embedded in the thylakoid membrane of plants and cyanobacteria, which transfer light energy to one chlorophyll a molecule at the reaction center of a photosystem. The antenna pigments are predominantly chlorophyll b, xanthophylls, and ...
The long-lived triplet excited state accessible by photoexcitation is both a more potent reducing agent and a more potent oxidizing agent than the ground state of the catalyst. Since sensitizer is coordinatively saturated, electron transfer must occur by an outer sphere process, where the electron tunnels between the catalyst and the substrate.
Examples of atoms in singlet, doublet, and triplet states. In quantum mechanics, a triplet state, or spin triplet, is the quantum state of an object such as an electron, atom, or molecule, having a quantum spin S = 1. It has three allowed values of the spin's projection along a given axis m S = −1, 0, or +1, giving the name "triplet".
Fluorescence microscopy relies upon fluorescent compounds, or fluorophores, in order to image biological systems.Since fluorescence and phosphorescence are competitive methods of relaxation, a fluorophore that undergoes intersystem crossing to the triplet excited state no longer fluoresces and instead remains in the triplet excited state, which has a relatively long lifetime, before ...
Hexazinone binds to a protein of the photosystem II complex, which blocks the electron transport. The result are multiple following reactions. The result are multiple following reactions. First triplet-state chlorophyll reacts with oxygen to form singlet oxygen .
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