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  2. Molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Molecular_geometry

    A bond angle is the angle formed between three atoms across at least two bonds. For four atoms bonded together in a chain, the torsional angle is the angle between the plane formed by the first three atoms and the plane formed by the last three atoms. There exists a mathematical relationship among the bond angles for one central atom and four ...

  3. VSEPR theory - Wikipedia

    en.wikipedia.org/wiki/VSEPR_theory

    Example of bent electron arrangement (water molecule). Shows location of unpaired electrons, bonded atoms, and bond angles. The bond angle for water is 104.5°. Valence shell electron pair repulsion (VSEPR) theory (/ ˈ v ɛ s p ər, v ə ˈ s ɛ p ər / VESP-ər, [1]: 410 və-SEP-ər [2]) is a model used in chemistry to predict the geometry of ...

  4. Bent's rule - Wikipedia

    en.wikipedia.org/wiki/Bent's_rule

    According to VSEPR theory, diethyl ether, methanol, water and oxygen difluoride should all have a bond angle of 109.5 o. [12] Using VSEPR theory, all these molecules should have the same bond angle because they have the same "bent" shape. [12] Yet, clearly the bond angles between all these molecules deviate from their ideal geometries in ...

  5. Bent molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Bent_molecular_geometry

    The bond angle between the two hydrogen atoms is approximately 104.45°. [1] Nonlinear geometry is commonly observed for other triatomic molecules and ions containing only main group elements, prominent examples being nitrogen dioxide (NO 2), sulfur dichloride (SCl 2), and methylene (CH 2).

  6. Trigonal bipyramidal molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Trigonal_bipyramidal...

    In chemistry, a trigonal bipyramid formation is a molecular geometry with one atom at the center and 5 more atoms at the corners of a triangular bipyramid. [1] This is one geometry for which the bond angles surrounding the central atom are not identical (see also pentagonal bipyramid), because there is no geometrical arrangement with five terminal atoms in equivalent positions.

  7. Chemical bonding of water - Wikipedia

    en.wikipedia.org/wiki/Chemical_bonding_of_water

    As such, the predicted shape and bond angle of sp 3 hybridization is tetrahedral and 109.5°. This is in open agreement with the true bond angle of 104.45°. The difference between the predicted bond angle and the measured bond angle is traditionally explained by the electron repulsion of the two lone pairs occupying two sp 3 hybridized orbitals.

  8. Pentagonal bipyramidal molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Pentagonal_bipyramidal...

    The pentagonal bipyramid is a case where bond angles surrounding an atom are not identical (see also trigonal bipyramidal molecular geometry). [1] [page needed] This is one of the three common shapes for heptacoordinate transition metal complexes, along with the capped octahedron and the capped trigonal prism. [2] [3] [page needed]

  9. Tetrahedral molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Tetrahedral_molecular_geometry

    In a tetrahedral molecular geometry, a central atom is located at the center with four substituents that are located at the corners of a tetrahedron.The bond angles are arccos(− ⁠ 1 / 3 ⁠) = 109.4712206...° ≈ 109.5° when all four substituents are the same, as in methane (CH 4) [1] [2] as well as its heavier analogues.