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In organic chemistry, an acyl chloride (or acid chloride) is an organic compound with the functional group −C(=O)Cl. Their formula is usually written R−COCl, where R is a side chain. They are reactive derivatives of carboxylic acids (R−C(=O)OH). A specific example of an acyl chloride is acetyl chloride, CH 3 COCl.
Weak bases are better leaving groups than strong bases; a species with a strong conjugate acid (e.g. hydrochloric acid) will be a better leaving group than a species with a weak conjugate acid (e.g. acetic acid). Thus, chloride ion is a better leaving group than acetate ion. The reactivity of acyl compounds towards nucleophiles decreases as the ...
Water conditioners are formulations designed to be added to tap water before its use in an aquarium. [1] [2] If the tap water is chlorinated then a simple conditioner containing a dechlorinator may be used. These products contain sodium thiosulfate which reduces chlorine to chloride which is less harmful to fish.
The reactivity of chloroformates and acyl chlorides are similar. Representative reactions are: Reaction with amines to form carbamates: [2] ROC(O)Cl + H 2 NR' → ROC(O)-N(H)R' + HCl. Reaction with alcohols to form carbonate esters: ROC(O)Cl + HOR' → ROC(O)-OR' + HCl. Reaction with carboxylic acids to form mixed anhydrides:
Acetyl chloride was first prepared in 1852 by French chemist Charles Gerhardt by treating potassium acetate with phosphoryl chloride. [4]Acetyl chloride is produced in the laboratory by the reaction of acetic acid with chlorodehydrating agents such as phosphorus trichloride (PCl 3), phosphorus pentachloride (PCl 5), sulfuryl chloride (SO 2 Cl 2), phosgene, or thionyl chloride (SOCl 2).
Pages in category "Acyl chlorides" The following 40 pages are in this category, out of 40 total. This list may not reflect recent changes. ...
Benzoyl chloride, also known as benzenecarbonyl chloride, is an organochlorine compound with the formula C 7 H 5 ClO. It is a colourless, fuming liquid with an irritating odour, and consists of a benzene ring ( C 6 H 6 ) with an acyl chloride ( −C(=O)Cl ) substituent .
In chemistry, acylation is a broad class of chemical reactions in which an acyl group (R−C=O) is added to a substrate. The compound providing the acyl group is called the acylating agent. The substrate to be acylated and the product include the following: alcohols, esters; amines, amides; arenes or alkenes, [1] ketones
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