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For gases, departure from 3 R per mole of atoms is generally due to two factors: (1) failure of the higher quantum-energy-spaced vibration modes in gas molecules to be excited at room temperature, and (2) loss of potential energy degree of freedom for small gas molecules, simply because most of their atoms are not bonded maximally in space to ...
It is defined as one kilocalorie of energy (1000 thermochemical gram calories) per one mole of substance. The unit symbol is written kcal/mol or kcal⋅mol −1. As typically measured, one kcal/mol represents a temperature increase of one degree Celsius in one liter of water (with a mass of 1 kg) resulting from the reaction of one mole of reagents.
The SI unit of molar heat capacity is joule per kelvin per mole, J⋅K −1 ⋅mol −1. Like the specific heat, the measured molar heat capacity of a substance, especially a gas, may be significantly higher when the sample is allowed to expand as it is heated ( at constant pressure , or isobaric ) than when it is heated in a closed vessel that ...
7 N nitrogen (N 2) use ... (per mol N atoms) 0.36 8 O oxygen (O 2) use (O 2) 0.444 CRC (O 2 ... Values refer to the enthalpy change between the liquid phase and the ...
All values refer to 25 °C and to the thermodynamically stable standard state at that temperature unless noted. Values from CRC refer to "100 kPa (1 bar or 0.987 standard atmospheres)".
[1] For a fuel of composition C c H h O o N n, the (higher) heat of combustion is 419 kJ/mol × (c + 0.3 h − 0.5 o) usually to a good approximation (±3%), [2] [3] though it gives poor results for some compounds such as (gaseous) formaldehyde and carbon monoxide, and can be significantly off if o + n > c, such as for glycerine dinitrate, C 3 ...
1.358 0.02789 Nitrogen: 1.370 0.0387 Nitrogen dioxide: 5.354 0.04424 Nitrogen trifluoride [2] 3.58 0.0545 Nitrous oxide: 3.832 0.04415 Octane [2] 37.88 0.2374 1-Octanol [2] 44.71 0.2442 Oxygen: 1.382 0.03186 Ozone [2] 3.570 0.0487 Pentane: 19.26 0.146 1-Pentanol [2] 25.88 0.1568 Phenol [2] 22.93 0.1177 Phosphine: 4.692 0.05156 Propane: 8.779 0. ...
Macroscopically, the ideal gas law states that, for an ideal gas, the product of pressure p and volume V is proportional to the product of amount of substance n and absolute temperature T: =, where R is the molar gas constant (8.314 462 618 153 24 J⋅K −1 ⋅mol −1). [4]