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The degree of reaction contributes to the stage efficiency and thus used as a design parameter. Stages having 50% degree of reaction are used where the pressure drop is equally shared by the stator and the rotor for a turbine. Figure 4. Velocity triangle for Degree of Reaction = 1/2 in a turbine
In physical chemistry, the Arrhenius equation is a formula for the temperature dependence of reaction rates.The equation was proposed by Svante Arrhenius in 1889, based on the work of Dutch chemist Jacobus Henricus van 't Hoff who had noted in 1884 that the van 't Hoff equation for the temperature dependence of equilibrium constants suggests such a formula for the rates of both forward and ...
The kinetics of rapid reactions can be studied with the temperature jump method. This involves using a sharp rise in temperature and observing the relaxation time of the return to equilibrium. A particularly useful form of temperature jump apparatus is a shock tube, which can rapidly increase a gas's temperature by more than 1000 degrees.
In most cases of interest in chemical thermodynamics there are internal degrees of freedom and processes, such as chemical reactions and phase transitions, which create entropy in the universe unless they are at equilibrium or are maintained at a "running equilibrium" through "quasi-static" changes by being coupled to constraining devices, such ...
Physical chemistry, in contrast to chemical physics, is predominantly (but not always) a supra-molecular science, as the majority of the principles on which it was founded relate to the bulk rather than the molecular or atomic structure alone (for example, chemical equilibrium and colloids).
[1] [2] The third law is also more generally stated as: "To every action there is always opposed an equal reaction: or the mutual actions of two bodies upon each other are always equal, and directed to contrary parts." [3] The attribution of which of the two forces is the action and which is the reaction is arbitrary. Either of the two can be ...
Conversion and its related terms yield and selectivity are important terms in chemical reaction engineering.They are described as ratios of how much of a reactant has reacted (X — conversion, normally between zero and one), how much of a desired product was formed (Y — yield, normally also between zero and one) and how much desired product was formed in ratio to the undesired product(s) (S ...
In physics and chemistry, a degree of freedom is an independent physical parameter in the chosen parameterization of a physical system.More formally, given a parameterization of a physical system, the number of degrees of freedom is the smallest number of parameters whose values need to be known in order to always be possible to determine the values of all parameters in the chosen ...