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Sodium ferrocyanide is the sodium salt of the coordination compound of formula [Fe(CN) 6] 4−. In its hydrous form, Na 4 Fe(CN) 6 · H 2 O (sodium ferrocyanide decahydrate), it is sometimes known as yellow prussiate of soda. It is a yellow crystalline solid that is soluble in water and insoluble in alcohol. The yellow color is the color of ...
Ferrocyanide is the name of the anion [Fe 6] 4−. Salts of this coordination complex give yellow solutions. It is usually available as the salt potassium ferrocyanide, which has the formula K 4 Fe(CN) 6. [Fe(CN) 6] 4− is a diamagnetic species, featuring low-spin iron(II) center in an octahedral ligand environment.
Ferroxyl indicator, or rust indicator, is a solution containing potassium hexacyanoferrate(III), phenolphthalein and sodium chloride. It turns blue in the presence of Fe 2+ ions, and pink in the presence of hydroxide (OH −) ions. It can be used to detect metal oxidation, and is often used to detect rusting in various situations.
The iron is low spin and easily reduced to the related ferrocyanide ion [Fe(CN) 6] 4−, which is a ferrous (Fe 2+) derivative. This redox couple is reversible and entails no making or breaking of Fe–C bonds: [Fe(CN) 6] 3− + e − ⇌ [Fe(CN) 6] 4−. This redox couple is a standard in electrochemistry.
Some anticaking agents function by absorbing excess moisture or by coating particles and making them water-repellent. Calcium silicate (CaSiO 3), a commonly used anti-caking agent, added to e.g. table salt, absorbs both water and oil. Anticaking agents are also used in non-food items such as road salt, [3] fertilisers, [4] cosmetics, [5] [6 ...
Potassium hexacyanidoferrate(II) finds many niche applications in industry. It and the related sodium salt are widely used as anticaking agents for both road salt and table salt. The potassium and sodium hexacyanidoferrates(II) are also used in the purification of tin and the separation of copper from molybdenum ores.
Prussian white, also known as Berlin white or Everett's salt, is the sodium end-member of the totally reduced form of the Prussian blue in which all iron is present as Fe(II). It is a sodium hexacyanoferrate of Fe(II) of formula Na 2 Fe[Fe(CN) 6]. [29] Its molecular weight value is 314 g/mol. [29]
Coagulation-flocculation process in a water treatment system. In water treatment, coagulation and flocculation involve the addition of compounds that promote the clumping of fine floc into larger floc so that they can be more easily separated from the water. Coagulation is a chemical process that involves neutralization of charge whereas ...