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In finance, bond convexity is a measure of the non-linear relationship of bond prices to changes in interest rates, and is defined as the second derivative of the price of the bond with respect to interest rates (duration is the first derivative). In general, the higher the duration, the more sensitive the bond price is to the change in ...
The bond angles in the table below are ideal angles from the simple VSEPR theory (pronounced "Vesper Theory") [citation needed], followed by the actual angle for the example given in the following column where this differs. For many cases, such as trigonal pyramidal and bent, the actual angle for the example differs from the ideal angle, and ...
This angle may be calculated from the dot product of the two vectors, defined as a ⋅ b = ‖ a ‖ ‖ b ‖ cos θ where ‖ a ‖ denotes the length of vector a. As shown in the diagram, the dot product here is –1 and the length of each vector is √ 3, so that cos θ = – 1 / 3 and the tetrahedral bond angle θ = arccos ...
The drawback of this approach is that the equations may become unwieldy and complex; for example, the mass matrix M may become non-diagonal and depend on the generalized coordinates. A second approach is to introduce explicit forces that work to maintain the constraint; for example, one could introduce strong spring forces that enforce the ...
Yet, clearly the bond angles between all these molecules deviate from their ideal geometries in different ways. Bent's rule can help elucidate these apparent discrepancies. [5] [20] [21] Electronegative substituents will have more p character. [5] [20] Bond angle has a proportional relationship with s character and an inverse relationship with ...
In chemistry, the Z-matrix is a way to represent a system built of atoms.A Z-matrix is also known as an internal coordinate representation.It provides a description of each atom in a molecule in terms of its atomic number, bond length, bond angle, and dihedral angle, the so-called internal coordinates, [1] [2] although it is not always the case that a Z-matrix will give information regarding ...
In mathematics, the modulus of convexity and the characteristic of convexity are measures of "how convex" the unit ball in a Banach space is. In some sense, the modulus of convexity has the same relationship to the ε - δ definition of uniform convexity as the modulus of continuity does to the ε - δ definition of continuity .
Another example is O(SiH 3) 2 with an Si–O–Si angle of 144.1°, which compares to the angles in Cl 2 O (110.9°), (CH 3) 2 O (111.7°), and N(CH 3) 3 (110.9°). [24] Gillespie and Robinson rationalize the Si–O–Si bond angle based on the observed ability of a ligand's lone pair to most greatly repel other electron pairs when the ligand ...
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