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Despite the foregoing, there is a difference between the two quantities. The information entropy Η can be calculated for any probability distribution (if the "message" is taken to be that the event i which had probability p i occurred, out of the space of the events possible), while the thermodynamic entropy S refers to thermodynamic probabilities p i specifically.
This quantity is the amount of entropy that may be increased without changing an internal energy or increasing its volume. [9] In other words, it is a difference between maximum possible, under assumed conditions, entropy and its actual entropy. It corresponds exactly to the definition of negentropy adopted in statistics and information theory.
Entropy can also be defined for any Markov processes with reversible dynamics and the detailed balance property. In Boltzmann's 1896 Lectures on Gas Theory, he showed that this expression gives a measure of entropy for systems of atoms and molecules in the gas phase, thus providing a measure for the entropy of classical thermodynamics.
The concept of information entropy was introduced by Claude Shannon in his 1948 paper "A Mathematical Theory of Communication", [2] [3] and is also referred to as Shannon entropy. Shannon's theory defines a data communication system composed of three elements: a source of data, a communication channel , and a receiver.
Thus, if entropy is associated with disorder and if the entropy of the universe is headed towards maximal entropy, then many are often puzzled as to the nature of the "ordering" process and operation of evolution in relation to Clausius' most famous version of the second law, which states that the universe is headed towards maximal "disorder".
Entropy is one of the few quantities in the physical sciences that require a particular direction for time, sometimes called an arrow of time. As one goes "forward" in time, the second law of thermodynamics says, the entropy of an isolated system can increase, but not decrease. Thus, entropy measurement is a way of distinguishing the past from ...
In information theory, the conditional entropy quantifies the amount of information needed to describe the outcome of a random variable given that the value of another random variable is known. Here, information is measured in shannons , nats , or hartleys .
The von Neumann entropy formula is an extension of the Gibbs entropy formula to the quantum mechanical case. It has been shown [ 1 ] that the Gibbs Entropy is equal to the classical "heat engine" entropy characterized by d S = δ Q T {\displaystyle dS={\frac {\delta Q}{T}}\!} , and the generalized Boltzmann distribution is a sufficient and ...