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Quantities, Units and Symbols in Physical Chemistry, also known as the Green Book, is a compilation of terms and symbols widely used in the field of physical chemistry. It also includes a table of physical constants , tables listing the properties of elementary particles , chemical elements , and nuclides , and information about conversion ...
Cartesian y-axis basis unit vector unitless kinetic energy: joule (J) wave vector: radian per meter (m −1) Boltzmann constant: joule per kelvin (J/K) wavenumber: radian per meter (m −1) stiffness: newton per meter (N⋅m −1) ^ Cartesian z-axis basis unit vector
Theoretical chemistry requires quantities from core physics, such as time, volume, temperature, and pressure.But the highly quantitative nature of physical chemistry, in a more specialized way than core physics, uses molar amounts of substance rather than simply counting numbers; this leads to the specialized definitions in this article.
kT (also written as k B T) is the product of the Boltzmann constant, k (or k B), and the temperature, T.This product is used in physics as a scale factor for energy values in molecular-scale systems (sometimes it is used as a unit of energy), as the rates and frequencies of many processes and phenomena depend not on their energy alone, but on the ratio of that energy and kT, that is, on E ...
"The kelvin, symbol K, is the SI unit of thermodynamic temperature. It is defined by taking the fixed numerical value of the Boltzmann constant k to be 1.380 649 × 10 −23 when expressed in the unit J K −1, which is equal to kg m 2 s −2 K −1, where the kilogram, metre and second are defined in terms of h, c and ∆ν Cs." [1]
Also acid ionization constant or acidity constant. A quantitative measure of the strength of an acid in solution expressed as an equilibrium constant for a chemical dissociation reaction in the context of acid-base reactions. It is often given as its base-10 cologarithm, p K a. acid–base extraction A chemical reaction in which chemical species are separated from other acids and bases. acid ...
In physics, natural unit systems are measurement systems for which selected physical constants have been set to 1 through nondimensionalization of physical units.For example, the speed of light c may be set to 1, and it may then be omitted, equating mass and energy directly E = m rather than using c as a conversion factor in the typical mass–energy equivalence equation E = mc 2.
Such tests are usually done isothermally (at constant temperature) by changing the atmosphere of the sample. First, the sample is brought to the desired test temperature under an inert atmosphere, usually nitrogen. Oxygen is then added to the system. Any oxidation that occurs is observed as a deviation in the baseline.