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An irreversible process increases the total entropy of the system and its surroundings. The second law of thermodynamics can be used to determine whether a hypothetical process is reversible or not. Intuitively, a process is reversible if there is no dissipation. For example, Joule expansion is irreversible because initially the system is not ...
In maximum parsimony, Dollo parsimony refers to a model whereby a characteristic is gained only one time and can never be regained if it is lost. [8] For example, the evolution and repeated loss of teeth in vertebrates could be well-modeled under Dollo parsimony, whereby teeth made from hydroxyapatite evolved only once at the origin of vertebrates, and were then lost multiple times, in birds ...
In physics, Loschmidt's paradox (named for J.J. Loschmidt), also known as the reversibility paradox, irreversibility paradox, or Umkehreinwand (from German 'reversal objection'), [1] is the objection that it should not be possible to deduce an irreversible process from time-symmetric dynamics.
Every process occurring in nature proceeds in the sense in which the sum of the entropies of all bodies taking part in the process is increased. In the limit, i.e. for reversible processes, the sum of the entropies remains unchanged. [42] [43] [44] Rather like Planck's statement is that of George Uhlenbeck and G. W. Ford for irreversible phenomena.
In physics, transport phenomena are all irreversible processes of statistical nature stemming from the random continuous motion of molecules, mostly observed in fluids. Every aspect of transport phenomena is grounded in two primary concepts : the conservation laws, and the constitutive equations.
The suitable relationship that defines non-equilibrium thermodynamic state variables is as follows. When the system is in local equilibrium, non-equilibrium state variables are such that they can be measured locally with sufficient accuracy by the same techniques as are used to measure thermodynamic state variables, or by corresponding time and space derivatives, including fluxes of matter and ...
The entropy-production rate of every process in nature is always positive or zero. This is an essential aspect of the second law. The Σ's indicate the algebraic sum of the respective contributions if there are more heat flows, matter flows, and internal processes.
For his study in irreversible thermodynamics, he received the Rumford Medal in 1976, and in 1977, the Nobel Prize in Chemistry "for his contributions to non-equilibrium thermodynamics, particularly the theory of dissipative structures". [6] In 1989, he was awarded the title of viscount in the Belgian nobility by the King of the Belgians. Until ...