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One example is the Suzuki reaction where, in the presence of a Pd(0) catalyst and base, phenylboronic acid and vinyl halides are coupled to produce phenyl alkenes. [7] This method was generalized to a route producing biaryls by coupling phenylboronic acid with aryl halides. C-C bond forming processes commonly use phenylboronic acid as a reagent.
4-Nonylphenylboronic acid is a potent and selective inhibitor of the enzyme fatty acid amide hydrolase (FAAH), with an IC 50 of 9.1nM, and 870x selectivity for FAAH over the related enzyme MAGL, which it inhibits with an IC 50 of 7900nM. [1]
4-Formylphenyl boronic acid crystallizes in colorless needles [1] or is obtained as an odorless, whitish powder, which dissolves little in cold but better in hot water. The compound is quite stable [3] and readily forms dimers and cyclic trimeric anhydrides, which complicate purification and tend to protodeboronize, a secondary reaction that occurs frequently in the Suzuki coupling, with ...
A boronic acid is an organic compound related to boric acid (B(OH) 3) in which one of the three hydroxyl groups (−OH) is replaced by an alkyl or aryl group (represented by R in the general formula R−B(OH) 2). [1] As a compound containing a carbon–boron bond, members of this class thus belong to the larger class of organoboranes.
98.4 [9] Isobutanol: 107.7 [10] n-Hexane: 0.66 68.7 [11] n-Butanol: 117.7 [12] Hydrochloric Acid: 84.8 [13] tert-Butanol: 82.5 [14] Chlorobenzene: 131.7 [15] p-chlorobenzotrifluoride: 1.34 136 –36.1 [16] MTBE: 55.2 [17] Pentane: 36.1 [18] Petroleum Ether: 35.0-60.0 [19] Cyclopentane: 49.3 [20] Isopropanol: 82.3 [21] Dichloromethane: 1.33 39.8 ...
The mixture of nonylphenol isomers is a pale yellow liquid, although the pure compounds are colorless. The nonylphenols are moderately soluble in water [ 12 ] but soluble in alcohol. Nonylphenol arises from the environmental degradation of nonylphenol ethoxylates , which are the metabolites of commercial detergents called alkylphenol ethoxylates.
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The R−C(=O)O part is then named as a separate word based on the carboxylic acid name, with the ending changed from "-oic acid" to "-oate" or "-carboxylate" For example, CH 3 CH 2 CH 2 CH 2 COOCH 3 is methyl pentanoate, and (CH 3) 2 CHCH 2 CH 2 COOCH 2 CH 3 is ethyl 4-methylpentanoate.