Search results
Results from the WOW.Com Content Network
Dimethyldichlorosilane is a tetrahedral organosilicon compound with the formula Si(CH 3) 2 Cl 2. At room temperature it is a colorless liquid that readily reacts with water to form both linear and cyclic Si-O chains. Dimethyldichlorosilane is made on an industrial scale as the principal precursor to dimethylsilicone and polysilane compounds.
Stock and Somieski completed the hydrolysis of dichlorosilane by putting the solution of H 2 SiCl 2 in benzene in brief contact with a large excess of water. [3] [5] A large-scale hydrolysis was done in a mixed ether/alkane solvent system at 0 °C, which gave a mixture of volatile and nonvolatile [H 2 SiO] n.
2 ((CH 3) 3 SiCl + H 2 O → [(CH 3) 3 Si] 2 O + 2 HCl. The analogous reaction of dimethyldichlorosilane gives siloxane polymers or rings: n (CH 3) 2 SiCl 2 + n H 2 O → [(CH 3) 2 SiO] n + 2n HCl. Many compounds containing Si-Cl bonds can be converted to hydrides using lithium aluminium hydride, This kind of conversion was demonstrated for the ...
2 CH 3 Cl + Si → (CH 3) 4−n SiCl n + other products While this reaction is the standard in industrial silicone production and is nearly identical to the first direct synthesis of methyltrichlorosilane, the overall process is inefficient with respect to methyltrichlorosilane. [ 2 ]
Chloro(dimethyl sulfide)gold(I) is commercially available. It may be prepared by dissolving gold in aqua regia (to give chloroauric acid), followed by addition of dimethyl sulfide. [2] Alternatively, sodium tetrachloroaurate may be used as the source of gold(III). [3] The bromo analog, Me 2 SAuBr, has also been synthesized by a similar route. [4]
The chemical formula of PDMS is CH 3 [Si(CH 3) 2 O] n Si(CH 3) 3, where n is the number of repeating monomer [Si(CH 3) 2 O] units. [4] Industrial synthesis can begin from dimethyldichlorosilane and water by the following net reaction: n Si(CH 3) 2 Cl 2 + (n+1) H 2 O → HO[Si(CH 3) 2 O] n H + 2n HCl. The polymerization reaction evolves ...
Note that the especially high molar values, as for paraffin, gasoline, water and ammonia, result from calculating specific heats in terms of moles of molecules. If specific heat is expressed per mole of atoms for these substances, none of the constant-volume values exceed, to any large extent, the theoretical Dulong–Petit limit of 25 J⋅mol ...
— "Values ranging from 21.3 to 21.5 gm/cm 3 at 20 °C have been reported for the density of annealed platinum; the best value being about 21.45 gm/cm 3 at 20 °C." 21.46 g/cm 3 — Rose, T. Kirke. The Precious Metals, Comprising Gold, Silver and Platinum .