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Sulfuryl chloride is used as a source of Cl 2.Because it is a pourable liquid, it is considered more convenient than Cl 2 to dispense.. Sulfuryl chloride is used in the conversion of C−H to C−Cl adjacent to activating substituents such as carbonyls and sulfoxides: [5] [6]
SCl 2 is used in organic synthesis.It adds to alkenes to give chloride-substituted thioethers. Illustrative is its addition to 1,5-cyclooctadiene to give a bicyclic thioether [2] A well tested method for the production of the mustard gas bis(2-chloroethyl)sulfide, is the addition of ethylene to sulfur dichloride: [3]
Sulfuryl chloride and chlorosulfuric acid are derivatives of sulfuric acid; thionyl chloride (SOCl 2) is a common reagent in organic synthesis. [7] Sulfur halides are precursors to a variety of metal complexes. [8]
Sulfuryl chloride fluoride is a chemical compound with the formula SO 2 ClF. It is a colorless, easily condensed gas. It is a tetrahedral molecule. Liquified sulfuryl chloride fluoride is employed as a solvent for highly oxidizing compounds. [1]
Schedule 3 substances, in the sense of the Chemical Weapons Convention, are chemicals which have large-scale industrial uses, but are feasible to use as toxic chemical weapons (Part A) or manufacturing precursors (Part B).
In chemistry, a sulfonyl halide consists of a sulfonyl (>S(=O) 2) group singly bonded to a halogen atom. They have the general formula RSO 2 X, where X is a halogen.The stability of sulfonyl halides decreases in the order fluorides > chlorides > bromides > iodides, all four types being well known.
The structure of the sulfuryl group. In inorganic chemistry, the sulfuryl group is a functional group consisting of a sulfur atom covalently bound to two oxygen atoms (S(=O) 2 X 2). It occurs in compounds such as sulfuryl chloride, SO 2 Cl 2 and sulfuryl fluoride, SO 2 F 2.
It is an intermediate, chemically and conceptually, between sulfuryl chloride (SO 2 Cl 2) and sulfuric acid (H 2 SO 4). [6] The compound is rarely obtained pure. Upon standing with excess sulfur trioxide, it decomposes to pyrosulfuryl chlorides: [7] 2 ClSO 3 H + SO 3 → H 2 SO 4 + S 2 O 5 Cl 2