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Its properties can be modified further by crosslinking or copolymerization. All forms are nontoxic as well as chemically resilient, contributing to polyethylene's popularity as a multi-use plastic. However, polyethylene's chemical resilience also makes it a long-lived and decomposition-resistant pollutant when disposed of improperly. [10]
In a similar way, the Phillips slurry process uses silica-based catalysts in contact with a fast-moving hydrocarbon and polyethylene slurry to precipitate high density polyethylene. [18] Processing will determine the properties of the HDPE. The method used to synthesize the HDPE is crucial because the micro structure of the HDPE will vary.
LDPE has SPI resin ID code 4 Schematic of LDPE branching structure. Low-density polyethylene (LDPE) is a thermoplastic made from the monomer ethylene.It was the first grade of polyethylene, produced in 1933 by Dr John C. Swallow and M.W Perrin who were working for Imperial Chemical Industries (ICI) using a high pressure process via free radical polymerization. [1]
The Properties of Polyethylene Crystallized Under the Orientation and Pressure Effects of a Pressure Capillary Viscometer, Journal of Applied Polymer Science vol. 14, pp. 2305–2317 (1970). Kanamoto, On Ultra-High Tensile by Drawing Single Crystal Mats of High Molecular Weight Polyethylene, Polymer Journal vol. 15, No. 4, pp. 327–329 (1983).
Linear low-density polyethylene (LLDPE) granules. Linear low-density polyethylene (LLDPE) is a substantially linear polymer (polyethylene), with significant numbers of short branches, commonly made by copolymerization of ethylene with longer-chain olefins.
A cross-linked polyethylene (PEX) pipe. Cross-linked polyethylene, commonly abbreviated PEX, XPE or XLPE, is a form of polyethylene with cross-links.It is used predominantly in building services pipework systems, hydronic radiant heating and cooling systems, domestic water piping, insulation for high tension (high voltage) electrical cables, and baby play mats.
List of some addition polymers and their uses ; Polymer Abbreviation Properties Uses Low-density polyethylene: LDPE: Chemically inert, flexible, insulator: Squeeze bottles, toys, flexible pipes, insulation cover (electric wires), six-pack rings, etc.
Medium-density polyethylene (MDPE) is a type of polyethylene defined by a density range of 0.926–0.940 g/cm 3. [1] It is less dense than HDPE, which is more common. MDPE can be produced by chromium/silica catalysts, Ziegler-Natta catalysts or metallocene catalysts. MDPE has good shock and drop resistance properties.