Search results
Results from the WOW.Com Content Network
The equilibrium concentration of each component in the liquid phase is often different from its concentration (or vapor pressure) in the vapor phase, but there is a relationship. The VLE concentration data can be determined experimentally or approximated with the help of theories such as Raoult's law , Dalton's law , and Henry's law .
The equilibrium vapor pressure is an indication of a liquid's thermodynamic tendency to evaporate. It relates to the balance of particles escaping from the liquid (or solid) in equilibrium with those in a coexisting vapor phase. A substance with a high vapor pressure at normal temperatures is often referred to as volatile. The pressure ...
The vapor pressure of water is the pressure exerted by molecules of water vapor in gaseous form (whether pure or in a mixture with other gases such as air). The saturation vapor pressure is the pressure at which water vapor is in thermodynamic equilibrium with its condensed state .
An ampule of nitrogen oxide vapor: brown nitrogen dioxide and colorless dinitrogen tetroxide, in equilibrium. In physics, a vapor (American English) or vapour (Commonwealth English; see spelling differences) is a substance in the gas phase at a temperature lower than its critical temperature, [1] which means that the vapor can be condensed to a liquid by increasing the pressure on it without ...
where P 1, P 2 are the vapor pressures at temperatures T 1, T 2 respectively, ΔH vap is the enthalpy of vaporization, and R is the universal gas constant. The rate of evaporation in an open system is related to the vapor pressure found in a closed system. If a liquid is heated, when the vapor pressure reaches the ambient pressure the liquid ...
The commonly known phases solid, liquid and vapor are separated by phase boundaries, i.e. pressure–temperature combinations where two phases can coexist. At the triple point, all three phases can coexist. However, the liquid–vapor boundary terminates in an endpoint at some critical temperature T c and critical pressure p c. This is the ...
Pressure of the equilibrium is given in the second column in kPa. The third column is the heat content of each gram of the liquid phase relative to water at 0 °C. The fourth column is the heat of vaporization of each gram of liquid that changes to vapor. The fifth column is the work PΔV done by each gram of liquid that changes to vapor. The ...
Boca Raton, Florida, 2003; Section 4, Properties of the Elements and Inorganic Compounds; Vapor Pressure of the Metallic Elements The equations reproduce the observed pressures to an accuracy of ±5% or better.