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2 Ge. Germanium cluster anions (Zintl ions) such as Ge 4 2−, Ge 9 4−, Ge 9 2−, [(Ge 9) 2] 6− have been prepared by the extraction from alloys containing alkali metals and germanium in liquid ammonia in the presence of ethylenediamine or a cryptand. [1] [3] The oxidation states of the element in these ions are not integers—similar to ...
A single-displacement reaction, also known as single replacement reaction or exchange reaction, is an archaic concept in chemistry. It describes the stoichiometry of some chemical reactions in which one element or ligand is replaced by an atom or group. [1] [2] [3] It can be represented generically as: + +
Atomic radius of elements of the groups 2, 13 and 14, showing the "d-block contraction", especially for Ga and Ge. The d-block contraction (sometimes called scandide contraction [1]) is a term used in chemistry to describe the effect of having full d orbitals on the period 4 elements.
The parent isotope germanium-68 is the longest-lived (271 days) of the radioisotopes of germanium. It has been produced by several methods. [1] In the U.S., it is primarily produced in proton accelerators: At Los Alamos National Laboratory, it may be separated out as a product of proton capture, after proton irradiation of Nb-encapsulated gallium metal. [2]
Germanium (32 Ge) has five naturally occurring isotopes, 70 Ge, 72 Ge, 73 Ge, 74 Ge, and 76 Ge. Of these, 76 Ge is very slightly radioactive, decaying by double beta decay with a half-life of 1.78 × 10 21 years [4] (130 billion times the age of the universe). Stable 74 Ge is the most common isotope, having a natural abundance of approximately 36%.
Coupled substitution is the geological process by which two elements simultaneous substitute into a crystal in order to maintain overall electrical neutrality and keep the charge constant. [1] In forming a solid solution series, ionic size is more important than ionic charge , as this can be compensated for elsewhere in the structure.
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