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Phosgene is an organic chemical compound with the formula COCl 2. It is a toxic, colorless gas; ... Some batch production does still take place, but efforts are made ...
Phosgene is the most dangerous commonly used pulmonary agent (although disulfur decafluoride and perfluoroisobutene are both even more dangerous, with respectively 4 and 10 times the lethality of phosgene, neither is widely used). It is a colorless gas under ordinary conditions.
Phosgene reacts with water to form carbon dioxide and HCl, [77] and the carbonate salt neutralizes the resulting acid. [ 78 ] Suspected samples can be tested for phosgene using filter paper which when treated with 5% diphenylamine , 5% dimethylaminobenzaldehyde in ethanol , and then dried, turns yellow in the presence of phosgene vapour. [ 79 ]
The daily Svenska Dagbladet newspaper said authorities had found traces of phosgene. The gas has a strong odor that can cause vomiting and breathing trouble and was used as a weapon in World War I.
Phosgene oxime is classified as a vesicant even though it does not produce blisters. [6] It is toxic by inhalation, ingestion, or skin contact. The effects of the poisoning occur almost immediately. No antidote for phosgene oxime poisoning is known. Generally, any treatment is supportive. Typical physical symptoms of CX exposure are as follows:
Phosphine (IUPAC name: phosphane) is a colorless, flammable, highly toxic compound with the chemical formula P H 3, classed as a pnictogen hydride.Pure phosphine is odorless, but technical grade samples have a highly unpleasant odor like rotting fish, due to the presence of substituted phosphine and diphosphane (P 2 H 4).
Diphosgene converts to phosgene upon heating or upon catalysis with charcoal. It is thus useful for reactions traditionally relying on phosgene. For example, it convert amines into isocyanates, secondary amines into carbamoyl chlorides, carboxylic acids into acid chlorides, and formamides into isocyanides. Diphosgene serves as a source of two ...
Death rates were high with exposure to both the mixed phosgene, chlorine and mustard gas, however with soldiers having readily available access to the small box respirator, death rates had lowered significantly. [3] Light and reasonably fitting, the respirator was a key piece of equipment to protect soldiers on the battlefield.