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  2. Enthalpy change of solution - Wikipedia

    en.wikipedia.org/wiki/Enthalpy_change_of_solution

    The integral heat of dissolution is defined as a process of obtaining a certain amount of solution with a final concentration. The enthalpy change in this process, normalized by the mole number of solute, is evaluated as the molar integral heat of dissolution. Mathematically, the molar integral heat of dissolution is denoted as:

  3. Thermodynamic databases for pure substances - Wikipedia

    en.wikipedia.org/wiki/Thermodynamic_databases...

    Enthalpy, heat content and heat capacity [ edit ] It is very difficult to measure the absolute amount of any thermodynamic quantity involving the internal energy (e.g. enthalpy ), since the internal energy of a substance can take many forms, each of which has its own typical temperature at which it begins to become important in thermodynamic ...

  4. Heat of dilution - Wikipedia

    en.wikipedia.org/wiki/Heat_of_dilution

    The heat of dilution can be defined from two perspectives: the differential heat and the integral heat. The differential heat of dilution is viewed on a micro scale, which is associated with the process in which a small amount of solvent is added to a large quantity of solution. The molar differential heat of dilution is thus defined as the enthalpy

  5. Standard state - Wikipedia

    en.wikipedia.org/wiki/Standard_state

    The standard state of a material (pure substance, mixture or solution) is a reference point used to calculate its properties under different conditions.A degree sign (°) or a superscript Plimsoll symbol (⦵) is used to designate a thermodynamic quantity in the standard state, such as change in enthalpy (ΔH°), change in entropy (ΔS°), or change in Gibbs free energy (ΔG°).

  6. Van 't Hoff equation - Wikipedia

    en.wikipedia.org/wiki/Van_'t_Hoff_equation

    The Van 't Hoff equation relates the change in the equilibrium constant, K eq, of a chemical reaction to the change in temperature, T, given the standard enthalpy change, Δ r H ⊖, for the process.

  7. Enthalpy of mixing - Wikipedia

    en.wikipedia.org/wiki/Enthalpy_of_mixing

    In thermodynamics, the enthalpy of mixing (also heat of mixing and excess enthalpy) is the enthalpy liberated or absorbed from a substance upon mixing. [1] When a substance or compound is combined with any other substance or compound, the enthalpy of mixing is the consequence of the new interactions between the two substances or compounds. [1]

  8. Thermochemical equation - Wikipedia

    en.wikipedia.org/wiki/Thermochemical_equation

    In thermochemistry, a thermochemical equation is a balanced chemical equation that represents the energy changes from a system to its surroundings.One such equation involves the enthalpy change, which is denoted with In variable form, a thermochemical equation would appear similar to the following:

  9. Gibbs–Helmholtz equation - Wikipedia

    en.wikipedia.org/wiki/Gibbs–Helmholtz_equation

    The definition of the Gibbs function is = + where H is the enthalpy defined by: = +. Taking differentials of each definition to find dH and dG, then using the fundamental thermodynamic relation (always true for reversible or irreversible processes): = where S is the entropy, V is volume, (minus sign due to reversibility, in which dU = 0: work other than pressure-volume may be done and is equal ...