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Nitric acid is an inorganic compound with the formula H N O 3. It is a highly corrosive mineral acid. [6] The compound is colorless, but samples tend to acquire a yellow cast over time due to decomposition into oxides of nitrogen. Most commercially available nitric acid has a concentration of 68% in water.
The pH of a simple solution of an acid in water is determined by both and the acid concentration. For weak acid solutions, it depends on the degree of dissociation, which may be determined by an equilibrium calculation. For concentrated solutions of acids, especially strong acids for which pH < 0, the value is a better measure of acidity than ...
Nitric acid, with a pK value of around −1.7, behaves as a strong acid in aqueous solutions with a pH greater than 1. [23] At lower pH values it behaves as a weak acid. p K a values for strong acids have been estimated by theoretical means. [ 24 ]
Upon mixing of concentrated hydrochloric acid and concentrated nitric acid, chemical reactions occur. These reactions result in the volatile products nitrosyl chloride and chlorine gas: HNO 3 + 3 HCl → NOCl + Cl 2 + 2 H 2 O. as evidenced by the fuming nature and characteristic yellow color of aqua regia.
Indeed silver nitrate can be prepared by dissolving silver in nitric acid followed by evaporation of the solution. The stoichiometry of the reaction depends upon the concentration of nitric acid used. 3 Ag + 4 HNO 3 (cold and diluted) → 3 AgNO 3 + 2 H 2 O + NO Ag + 2 HNO 3 (hot and concentrated) → AgNO 3 + H 2 O + NO 2
For example, copper is a rather unreactive metal, and has no reaction with concentrated hydrochloric acid. However, even dilute nitric acid can oxidize copper to Cu 2+ ions, with the nitrate ions acting as the effective oxidant: [1] 3 Cu + 8 HNO 3 → 3 Cu 2+ + 2 NO + 4 H 2 O + 6 NO − 3. Sometimes the concentration of the acid is a factor for ...
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The xanthoproteic reaction is a method that can be used to detect a presence of protein soluble in a solution, using concentrated nitric acid. The test gives a positive result in amino acids carrying aromatic groups, especially in the presence of tyrosine. If the test is positive the proof is neutralized with an alkali, turning dark yellow.