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A stirred BZ reaction mixture showing changes in color over time. The discovery of the phenomenon is credited to Boris Belousov.In 1951, while trying to find the non-organic analog to the Krebs cycle, he noted that in a mix of potassium bromate, cerium(IV) sulfate, malonic acid, and citric acid in dilute sulfuric acid, the ratio of concentration of the cerium(IV) and cerium(III) ions ...
The Oregonator is a theoretical model for a type of autocatalytic reaction. The Oregonator is the simplest realistic model of the chemical dynamics of the oscillatory Belousov–Zhabotinsky reaction. [1] It was created by Richard Field and Richard M. Noyes at the University of Oregon. [2] It is a portmanteau of Oregon and oscillator.
A Belousov–Zhabotinsky reaction is one of several oscillating chemical systems, whose common element is the inclusion of bromine and an acid. An essential aspect of the BZ reaction is its so-called "excitability"—under the influence of stimuli, patterns develop in what would otherwise be a perfectly quiescent medium.
A chemical computer, also called a reaction-diffusion computer, Belousov–Zhabotinsky (BZ) computer, or gooware computer, is an unconventional computer based on a semi-solid chemical "soup" where data are represented by varying concentrations of chemicals. [1] The computations are performed by naturally occurring chemical reactions.
While stable periodic solutions are unusual in real-world chemical reaction networks, well-known examples exist, such as the Belousov–Zhabotinsky reactions. The simplest catalytic oscillator (nonlinear self-oscillations without autocatalysis) can be produced from the catalytic trigger by adding a "buffer" step. [23]
Reaction–diffusion systems are naturally applied in chemistry. However, the system can also describe dynamical processes of non-chemical nature. Examples are found in biology, geology and physics (neutron diffusion theory) and ecology. Mathematically, reaction–diffusion systems take the form of semi-linear parabolic partial differential ...
If spatial effects are taken into account through a reaction–diffusion equation, long-range correlations and spatially ordered patterns arise, [6] such as in the case of the Belousov–Zhabotinsky reaction. Systems with such dynamic states of matter that arise as the result of irreversible processes are dissipative structures.
A forest is an example of an excitable medium: if a wildfire burns through the forest, no fire can return to a burnt spot until the vegetation has gone through its refractory period and regrown. In chemistry, oscillating reactions are excitable media, for example the Belousov–Zhabotinsky reaction and the Briggs–Rauscher reaction.