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If the spectrum analyzer produces 250 000 FFT/s an FFT calculation is produced every 4 μs. For a 1024 point FFT a full spectrum is produced 1024 x (1/50 x 10 6), approximately every 20 μs. This also gives us our overlap rate of 80% (20 μs − 4 μs) / 20 μs = 80%. Comparison between Swept Max Hold and Realtime Persistence displays
A "full spectrum" analysis considers all the "peaks" within a spectrum. Conversely, selective ion monitoring (SIM) only monitors selected ions associated with a specific substance. This is done on the assumption that at a given retention time, a set of ions is characteristic of a certain compound. This is a fast and efficient analysis ...
Spectrum analyzer, a hardware device that measures the magnitude of an input signal versus frequency within the full frequency range of the instrument; Spectral theory, in mathematics, a theory that extends eigenvalues and eigenvectors to linear operators on Hilbert space, and more generally to the elements of a Banach algebra
An extracted-ion chromatogram is generated by separating the ions of interest from a data file containing the full mass spectrum over time after the fact; this is different from selected-ion chromatograms, discussed below, in which data is collected only for specific m/z values. A closely related term is extracted-compound chromatogram (ECC).
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Spectrum analysis, also referred to as frequency domain analysis or spectral density estimation, is the technical process of decomposing a complex signal into simpler parts. As described above, many physical processes are best described as a sum of many individual frequency components.
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The Fellgett advantage, also known as the multiplex principle, states that when obtaining a spectrum when measurement noise is dominated by detector noise (which is independent of the power of radiation incident on the detector), a multiplex spectrometer such as a Fourier-transform spectrometer will produce a relative improvement in signal-to ...