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Pressure swing adsorption (PSA) is a technique used to separate some gas species from a mixture of gases (typically air) under pressure according to the species' molecular characteristics and affinity for an adsorbent material.
Another method, pressure-swing distillation, relies on the fact that an azeotrope is pressure dependent. An azeotrope is not a range of concentrations that cannot be distilled, but the point at which the activity coefficients of the distillates are crossing one another. If the azeotrope can be "jumped over", distillation can continue, although ...
The equation describing the relative motion is known as the swing equation, which is a non-linear second order differential equation that describes the swing of the rotor of synchronous machine. The power exchange between the mechanical rotor and the electrical grid due to the rotor swing (acceleration and deceleration) is called Inertial response.
This method can be continued indefinitely in the same way, where the order-n term consists of a harmonic term + (), plus some super-harmonic terms , +, +. The coefficients of the super-harmonic terms are solved directly, and the coefficients of the harmonic term are determined by expanding down to order-(n+1), and eliminating ...
The Freundlich isotherm has two parameters, while Langmuir's equations has only one: as a result, it often fits the data on rough surfaces better than the Langmuir isotherm. However, the Freundlich equation is not unique; consequently, a good fit of the data points does not offer sufficient proof that the surface is heterogeneous.
In computational chemistry, a constraint algorithm is a method for satisfying the Newtonian motion of a rigid body which consists of mass points. A restraint algorithm is used to ensure that the distance between mass points is maintained.
The simplest form of a group-contribution method is the determination of a component property by summing up the group contributions : [] = +.This simple form assumes that the property (normal boiling point in the example) is strictly linearly dependent on the number of groups, and additionally no interaction between groups and molecules are assumed.
Ab initio quantum chemistry methods are a class of computational chemistry techniques based on quantum chemistry that aim to solve the electronic Schrödinger equation. [1] Ab initio means "from first principles" or "from the beginning", meaning using only physical constants [2] and the positions and number of electrons in the system as input.