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The polarizability of an atom or molecule is defined as the ratio of its induced dipole moment to the local electric field; in a crystalline solid, one considers the dipole moment per unit cell. [1] Note that the local electric field seen by a molecule is generally different from the macroscopic electric field that would be measured externally.
Continuous charge distribution. The volume charge density ρ is the amount of charge per unit volume (cube), surface charge density σ is amount per unit surface area (circle) with outward unit normal nĚ‚, d is the dipole moment between two point charges, the volume density of these is the polarization density P.
The size of the induced dipole moment is equal to the product of the strength of the external field and the dipole polarizability of ρ. Dipole moment values can be obtained from measurement of the dielectric constant. Some typical gas phase values given with the unit debye are: [7] carbon dioxide: 0; carbon monoxide: 0.112 D; ozone: 0.53 D
Interaction energy of an argon dimer.The long-range section is due to London dispersion forces. London dispersion forces (LDF, also known as dispersion forces, London forces, instantaneous dipole–induced dipole forces, fluctuating induced dipole bonds [1] or loosely as van der Waals forces) are a type of intermolecular force acting between atoms and molecules that are normally electrically ...
In this equation, P is the (negative of the) field induced in the material when the "fixed" charges, the dipoles, shift in response to the total underlying field E, whereas D is the field due to the remaining charges, known as "free" charges. [5] [10] In general, P varies as a function of E depending on the medium, as described later in the ...
The source free equations can be written by the action of the exterior derivative on this 2-form. But for the equations with source terms (Gauss's law and the Ampère-Maxwell equation), the Hodge dual of this 2-form is needed. The Hodge star operator takes a p-form to a (n − p)-form, where n is the number of dimensions.
Maxwell's equations can directly give inhomogeneous wave equations for the electric field E and magnetic field B. [1] Substituting Gauss's law for electricity and Ampère's law into the curl of Faraday's law of induction, and using the curl of the curl identity ∇ × (∇ × X) = ∇(∇ ⋅ X) − ∇ 2 X (The last term in the right side is the vector Laplacian, not Laplacian applied on ...
Schwarzschild's equation is the formula by which you may calculate the intensity of any flux of electromagnetic energy after passage through a non-scattering medium when all variables are fixed, provided we know the temperature, pressure, and composition of the medium.