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Dimethyl sulfone (DMSO 2) is an organosulfur compound with the formula (CH 3) 2 SO 2. It is also known by several other names including methyl sulfone and (especially in alternative medicine) methylsulfonylmethane (MSM). [4] This colorless solid features the sulfonyl functional group and is the simplest of the sulfones. It is relatively inert ...
Dimethyl sulfide is used in the workup of the ozonolysis of alkenes. It reduces the intermediate trioxolane. The Swern oxidation produces dimethyl sulfide by reduction of dimethylsulfoxide. With chlorinating agents such as sulfuryl chloride, dimethyl sulfide converts to chloromethyl methyl sulfide: SO 2 Cl 2 + (CH 3) 2 S → SO 2 + HCl + ClCH 2 ...
Dimethyl ether: 8.180 0.07246 Dimethyl sulfide: ... Hydrogen chloride: 3.716 0.04081 Hydrogen cyanide [2] ... Sulfur dioxide: 6.803 0.05636
Methanesulfonyl chloride is mainly used to give methanesulfonates by its reaction with alcohols in the presence of a non-nucleophilic base. [8] In contrast to the formation of toluenesulfonates from alcohols and p-toluenesulfonyl chloride in the presence of pyridine, the formation of methanesulfonates is believed to proceed via a mechanism wherein methanesulfonyl chloride first undergoes an ...
Methanesulfinyl chloride, CH 3 S(O)Cl, is prepared by chlorination of dimethyl disulfide to give CH 3 SCl 3, which is treated with acetic anhydride. It is a straw-colored liquid. [3] Toluenesulfinyl chloride is prepared by treating sodium tosylate with thionyl chloride: [4] Also a straw-colored liquid, it boils near 100 °C at 0.5 mm Hg.
The intermediate benzenesulfonic acid can be chlorinated with thionyl chloride as well. Benzenesulfonyl chloride, the most important sulfonyl halide, can also be produced by treating sodium benzenesulfonate with phosphorus pentachlorides. [5] Benzenediazonium chloride reacts with sulfur dioxide and copper(I) chloride to give the sulfonyl chloride:
Hydrogen peroxide is a typical oxidant—for example, with dimethyl sulfide (S(CH 3) 2): [9] S(CH 3) 2 + H 2 O 2 → OS(CH 3) 2 + H 2 O OS(CH 3) 2 + H 2 O 2 → O 2 S(CH 3) 2 + H 2 O. In analogy to their easy alkylation, sulfides bind to metals to form thioether complexes. Consequently, Lewis acids do not decompose thioethers as they do ethers ...
Treatment of sulfur with hydrogen gives hydrogen sulfide.When dissolved in water, hydrogen sulfide is mildly acidic: [5] H 2 S ⇌ HS − + H +. Hydrogen sulfide gas and the hydrosulfide anion are extremely toxic to mammals, due to their inhibition of the oxygen-carrying capacity of hemoglobin and certain cytochromes in a manner analogous to cyanide and azide.