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The glass transition of a liquid to a solid-like state may occur with either cooling or compression. [10] The transition comprises a smooth increase in the viscosity of a material by as much as 17 orders of magnitude within a temperature range of 500 K without any pronounced change in material structure. [11]
These are made by the reaction of phenols, formaldehyde and primary amines which at elevated temperatures (400 °F (200 °C)) undergo ring–opening polymerisation forming polybenzoxazine thermoset networks; when hybridised with epoxy and phenolic resins the resulting ternary systems have glass transition temperatures in excess of 490 °F (250 °C).
Besides epoxy resins based on diglycidyl ... it solidifies at the glass-transition temperature T g. ... as the basis for coatings and composites reversibly bondable ...
New developments involving thermoset epoxy resins which on controlled and contained heating form crosslinked networks permit repeatedly reshaping, like silica glass by reversible covalent bond exchange reactions on reheating above the glass transition temperature. [11]
The resin and hardener part together is known as the "Binder". As the name indicates, in Fusion bonded epoxy coatings the resin part is an "epoxy" type resin. “Epoxy” or “Oxirane” structure contains a three membered cyclic ring — one oxygen atom connected to two carbon atoms – in the resin molecule. This part is the most reactive ...
Powder coating can also be removed by a burning off process, in which parts are put into a large high-temperature oven with temperatures typically reaching an air temperature of 300–450 °C. The process takes about four hours and requires the parts to be cleaned completely and re-powder coated.
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