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Water splitting is the chemical reaction in which water is broken down into oxygen and hydrogen: [1] 2 H 2 O → 2 H 2 + O 2 Efficient and economical water splitting would be a technological breakthrough that could underpin a hydrogen economy .
Photocatalysts must conform to several key principles in order to be considered effective at water splitting. A key principle is that H 2 and O 2 evolution should occur in a stoichiometric 2:1 ratio; significant deviation could be due to a flaw in the experimental setup and/or a side reaction, neither of which indicate a reliable photocatalyst for water splitting.
In the case of water electrolysis, Gibbs free energy represents the minimum work necessary for the reaction to proceed, and the reaction enthalpy is the amount of energy (both work and heat) that has to be provided so the reaction products are at the same temperature as the reactant (i.e. standard temperature for the values given above ...
The electrons from the initial light reaction reach Photosystem I, then are raised to a higher energy level by light energy and then received by an electron acceptor and reduce NADP + to NADPH. The electrons lost from Photosystem II get replaced by the oxidation of water, which is "split" into protons and oxygen by the oxygen-evolving complex ...
The high-energy oxidized tyrosine gives off its energy and returns to the ground state by taking up a proton and removing an electron from the oxygen-evolving complex and ultimately from water. [4] Kok's S-state diagram shows the reactions of water splitting in the oxygen-evolving complex.
2), a MO diagram may show one of the identical bonds to the central atom. For other polyatomic molecules, an MO diagram may show one or more bonds of interest in the molecules, leaving others out for simplicity. Often even for simple molecules, AO and MO levels of inner orbitals and their electrons may be omitted from a diagram for simplicity.
(One of the many mysteries of the human ovary that doesn’t have a ready explanation.) Despite the fact that half of the population has ovaries, this organ is still a bit of an enigma in the ...
Water is the most abundant substance on Earth's surface and also the third most abundant molecule in the universe, after H 2 and CO. [23] 0.23 ppm of the earth's mass is water and 97.39% of the global water volume of 1.38 × 10 9 km 3 is found in the oceans. [84]