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The onset of thermal degradation dictates the maximum temperature at which a polymer can be used. It is an important limitation in how the polymer is manufactured and processed. For instance, polymers become less viscous at higher temperatures which makes injection moulding easier and faster, but thermal degradation places a ceiling temperature ...
Polymers are composed of long molecular chains which form irregular, entangled coils in the melt. Some polymers retain such a disordered structure upon freezing and readily convert into amorphous solids. In other polymers, the chains rearrange upon freezing and form partly ordered regions with a typical size of the order 1 micrometer. [3]
Polymer solutions are solutions containing dissolved polymers. [1] These may be liquid solutions (e.g. in aqueous solution ), or solid solutions (e.g. a substance which has been plasticized). [ 2 ]
PET is hygroscopic and absorbs water. [33] About 60% crystallization is the upper limit for commercial products, with the exception of polyester fibers. [clarification needed] Transparent products can be produced by rapidly cooling molten polymer below the glass transition temperature (T g) to form a non-crystalline amorphous solid. [34]
It serves to repressurize the melt to get it through the resistance of the screens and the die. Often screw length is referenced to its diameter as L:D ratio. For instance, a 6-inch-diameter (150 mm) screw at 24:1 will be 144 inches (12 ft) long, and at 32:1 it is 192 inches (16 ft) long.
If the melt of an (organic) amorphous polymer is cooled down, it solidifies at the glass-transition temperature T g. On cooling, the hardness of the polymer increases in the neighborhood of T g by several orders of magnitude. This hardening follows the Williams-Landel-Ferry equation, not the Arrhenius equation.
The ability of the system to be readily deformed above its glass transition temperature allows polystyrene (and thermoplastic polymers in general) to be readily softened and molded upon heating. Extruded polystyrene is about as strong as an unalloyed aluminium but much more flexible and much less dense (1.05 g/cm 3 for polystyrene vs. 2.70 g/cm ...
Polycarbonate has a glass transition temperature of about 147 °C (297 °F), [8] so it softens gradually above this point and flows above about 155 °C (311 °F). [9] Tools must be held at high temperatures, generally above 80 °C (176 °F) to make strain-free and stress-free products.