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As a rule of thumb, the boiling point rises 20–30 °C for each carbon added to the chain; this rule applies to other homologous series. [18] A straight-chain alkane will have a boiling point higher than a branched-chain alkane due to the greater surface area in contact, and thus greater van der Waals forces, between adjacent molecules.
Higher alkanes are naturally present in crude oil and can be obtained via fractional distillation.Saturated fatty acids decarboxylate to higher alkanes. Long olefins can be hydrogenated to yield higher alkanes. n-alkanes can be isolated via the formation of urea clathrates.They can also be synthesized through Kolbe electrolysis or other coupling reactions like the Wurtz reaction.
Boiling point: 317 °C (603 °F; 590 K) Vapor pressure ... Octadecane is distinguished by being the alkane with the lowest carbon number that is unambiguously solid ...
Wiener showed that the Wiener index number is closely correlated with the boiling points of alkane molecules. [2] Later work on quantitative structure–activity relationships showed that it is also correlated with other quantities including the parameters of its critical point , [ 10 ] the density , surface tension , and viscosity of its ...
Hexadecane (also called cetane) is an alkane hydrocarbon with the chemical formula C 16 H 34. Hexadecane consists of a chain of 16 carbon atoms , with three hydrogen atoms bonded to the two end carbon atoms, and two hydrogens bonded to each of the 14 other carbon atoms.
2-Methylpentane, trivially known as isohexane, is a branched-chain alkane with the molecular formula C 6 H 14.It is a structural isomer of hexane composed of a methyl group bonded to the second carbon atom in a pentane chain.
In polymer chemistry, branching is the regular or irregular attachment of side chains to a polymer's backbone chain. It occurs by the replacement of a substituent (e.g. a hydrogen atom ) on a monomer subunit by another covalently-bonded chain of that polymer; or, in the case of a graft copolymer , by a chain of another type.
This Wikipedia page provides a comprehensive list of boiling and freezing points for various solvents.