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Phenylmagnesium bromide is a strong nucleophile as well as a strong base.It can abstract even mildly acidic protons, thus the substrate must be protected where necessary. It often adds to carbonyls, such as ketones, aldehyde
p-Methoxybenzyl (PMB) is used as a protecting group for alcohols in organic synthesis (4-Methoxybenzylthiol is used to protect thiols). The p -methoxybenzyl group Strong base such as powdered potassium hydroxide or sodium hydride and p -methoxybenzyl halide (chloride or bromide) [ 14 ] [ 15 ]
2,3-Dichloro-5,6-dicyano-1,4-benzoquinone (or DDQ) is the chemical reagent with formula C 6 Cl 2 (CN) 2 O 2. This oxidant is useful for the dehydrogenation of alcohols, [3] phenols, [4] and steroid ketones. [5] DDQ decomposes in water, but is stable in aqueous mineral acid. [6]
PMB can stand for: Phenylmagnesium bromide, a reagent; p-Methoxybenzyl, in the benzyl group; Nickname of Pietermaritzburg, KwaZulu-Natal, South Africa; Picture Motion Browser, Sony software; PMB (software), a library system; Postmenopausal bleeding, a menstrual condition; Print Measurement Bureau, a Canadian media surveying company
In many preparations of delicate organic compounds, specific parts of the molecules cannot survive the required reagents or chemical environments. These parts (functional groups) must be protected. For example, lithium aluminium hydride is a highly reactive reagent that usefully reduces esters to alcohols.
Para-methoxybenzyl (PMB) is a commonly used protecting group for alcohols against Fétizon's reagent. [15] As Fétizon's oxidation is a neutral reaction, acid and base sensitive protecting groups are also compatible with the reagent and by products generated.
The anion [Ce(NO 3) 6] 2− has T h (idealized O h) molecular symmetry.The CeO 12 core defines an icosahedron. [4]Ce 4+ is a strong one-electron oxidizing agent.In terms of its redox potential (E° ≈ 1.61 V vs. N.H.E.) it is an even stronger oxidizing agent than Cl 2 (E° ≈ 1.36 V).
Phosphomolybdic acid is the heteropolymetalate with the formula H 3 [Mo 12 PO 40]·12H 2 O.It is a yellow solid, although even slightly impure samples have a greenish coloration
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