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Unlike chlorates, which very slowly disproportionate to chloride and perchlorate, the bromate anion is stable to disproportionation in both acidic and aqueous solutions. Bromic acid is a strong acid. Bromides and bromates may comproportionate to bromine as follows: [49] BrO − 3 + 5 Br − + 6 H + → 3 Br 2 + 3 H 2 O
Unlike chlorates, which very slowly disproportionate to chloride and perchlorate, the bromate anion is stable to disproportionation in both acidic and aqueous solutions. Bromic acid is a strong acid. Bromides and bromates may comproportionate to bromine as follows: [13] BrO − 3 + 5 Br − + 6 H + → 3 Br 2 + 3 H 2 O
At 25 °C (77 °F), solutions with a pH less than 7 are acidic, and solutions with a pH greater than 7 are basic. Solutions with a pH of 7 at 25 °C are neutral (i.e. have the same concentration of H + ions as OH − ions, i.e. the same as pure water). The neutral value of the pH depends on the temperature and is lower than 7 if the temperature ...
Bromine readily reacts with water, i.e. it undergoes hydrolysis: Br 2 + H 2 O → HOBr + HBr. This forms hypobromous acid (HOBr), and hydrobromic acid (HBr in water). The solution is called "bromine water". The hydrolysis of bromine is more favorable in the presence of base, for example sodium hydroxide: Br 2 + NaOH → NaOBr + NaBr
When the acidic medium in question is a dilute aqueous solution, the is approximately equal to the pH value, which is a negative logarithm of the concentration of aqueous + in solution. The pH of a simple solution of an acid in water is determined by both K a {\displaystyle K_{{\ce {a}}}} and the acid concentration.
From numbers of equivalent portions of acid bromine formed from the previous reaction, the ratio between oxygen and bromine was calculated, with the exact value of O:Br (0.149975:0.3745), suggesting the acid compound contains two oxygen atom to one bromine atom. Thus, the chemical structure of the acid compound was deducted as HBrO 2. [2]
Bromic acid, also known as hydrogen bromate, is an oxoacid with the molecular formula HBrO 3. It only exists in aqueous solution. [1] [2] It is a colorless solution that turns yellow at room temperature as it decomposes to bromine. [1] [3] Bromic acid and bromates are powerful oxidizing agents and are common ingredients in Belousov ...
It is the bromine analogue of sodium hypochlorite, the active ingredient in common bleach. In practice the salt is usually encountered as an aqueous solution. Sodium hypobromite arises by treatment of aqueous solution of bromine with base: [2] Br 2 + 2 NaOH → NaBr + NaOBr + H 2 O