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Inverse spinel structures have a different cation distribution in that all of the A cations and half of the B cations occupy octahedral sites, while the other half of the B cations occupy tetrahedral sites. An example of an inverse spinel is Fe 3 O 4, if the Fe 2+ (A 2+) ions are d 6 high-spin and the Fe 3+ (B 3+) ions are d 5 high-spin.
The octahedral ion [Fe(NO 2) 6] 3−, which has 5 d-electrons, would have the octahedral splitting diagram shown at right with all five electrons in the t 2g level. This low spin state therefore does not follow Hund's rule. High Spin [FeBr 6] 3− crystal field diagram
Polyhedral representation of spinel MgAl 2 O 4. Spinel (/ s p ɪ ˈ n ɛ l, ˈ s p ɪ n əl / [7]) is the magnesium/aluminium member of the larger spinel group of minerals. It has the formula MgAl 2 O 4 in the cubic crystal system. Its name comes from the Latin word spinella, a diminutive form of spine, in reference to its pointed crystals. [5]
The diagram to the right shows edges for an equivalent unit cell with A in the cube corner position, B at the body center, and X at face-centered positions. Four general categories of cation-pairing are possible: A + B 2+ X − 3, or 1:2 perovskites; [8] A 2+ B 4+ X 2− 3, or 2:4 perovskites; A 3+ B 3+ X 2− 3, or 3:3 perovskites; and A + B 5 ...
The structure is inverse spinel, with O 2-ions forming a face-centered cubic lattice and iron cations occupying interstitial sites. Half of the Fe 3+ cations occupy tetrahedral sites while the other half, along with Fe 2+ cations, occupy octahedral sites. The unit cell consists of thirty-two O 2-ions and unit cell length is a = 0.839 nm. [15] [16]
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The orbital wave functions are positive in the red regions and negative in the blue. The right column shows virtual MO's which are empty in the ground state, but may be occupied in excited states. In chemistry , a molecular orbital ( / ɒr b ə d l / ) is a mathematical function describing the location and wave-like behavior of an electron in a ...
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